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. 2020 Sep 28;18(5):376–388. doi: 10.1089/bio.2019.0137

Table 1.

Compilation of Studies Describing the Stabilities of Clinical Analytes in Blood Specimens Under the Initial Handling/Storage Conditions Documented in This Study

Initial handling/storage conditions Biospecimen Stable analytes Unstable analytes Ref.
4°C for <3 hours (then −80°C) Serum   Folic acid 59
Plasma Ascorbic acid   60
Serum   Free PSA 61
Serum   ACTH 34
Whole blood   Potassium, glucose 62
4°C for 3–16 hours (then −80°C) Serum 13 fatty acids   59
Plasma Cell-free DNA   63
Serum   Free PSA 64
Serum   Transferrin receptor 32
Plasma/Serum   Ascorbic acid 36
Whole blood   Inorganic phosphorous, bicarbonate, lactate dehydrogenase, magnesium, APTT, C-telopeptide, ACTH 62
Plasma/Serum   Potassium, bicarbonate, lactate, glucose, magnesium, APTT, osteocalcin, C-telopeptide 62
4°C for >16 hours (then −80°C) Serum C-reactive protein, retinol, ferritin Fatty acids (13) 59
Plasma/serum Aldosterone, α-subunit total, α-subunit free, AVP, CRH, C-peptide, FSH, glucagon, GH, IGF-1, IGF-BP3, insulin, leptin, LH, PPP, PTH, prolactin, VIP   34
Plasma   ACTH 34
Plasma Vitamin B12 Folate 65
Serum Total PSA   64
Serum Total PSA, complex PSA   61
Serum Apolipoprotein E   66
Serum Cholesterol (IDL), triglycerides (VLDL, IDL), phospholipids (VLDL, IDL, LDL), proteins (VLDL, IDL, LDL, HDL) VLDL cholesterol, LDL cholesterol, LDL triglycerides, HDL cholesterol, HDL triglycerides, HDL phospholipids 67
Serum Palmitic acid, palmitoleic acid, stearic acid, oleic acid, linoleic acid, γ-linolenic acid, α-linolenic acid, dihomo-γ-linolenic acid, arachidonic acid, eicosapentaenoic acid, docosapentaenoic acid, docosahexaenoic acid, saturated fatty acid, mono unsaturated fatty acid, ω 3-polyunsaturated fatty acid, ω 6-polyunsaturated fatty acid Myristic acid 68
Plasma/Serum C-telopeptides of type I collagen (CTX)   69
Plasma   Cell-free DNA 63
Plasma   Catecholamines 70
Whole blood   Potassium 33
  Whole blood   Lactate, mean corpuscular volume, mean corpuscular hemoglobin, FSH, estradiol, prolactin, folate, insulin, C-peptide, PTH, osteocalcin 62
Plasma/Serum   Inorganic phosphorous, lactate dehydrogenase, FSH, estradiol, prolactin, folate, insulin, C-peptide, PTH 62
Plasma   Sphingosine (d18:1), sphingadienine (d18:2), sphingosine (d16:1), glycerate, 5-hydroxyeicosatetraenoic acid (C20:trans[6]cis[8,11,14]4) (5-HETE), threonic acid, 3,4-dihydroxyphenylacetic acid (DOPAC), 3,4-dihydroxyphenylglycol (DOPEG), Pentraxin-3, 10 peptides identified from fibrinogen, complement C4B and complement C3 71
−20°C for 2 months to 5 years Plasma Vitamin B6, vitamin B12, folic acid, vitamin D Vitamin A, carotenoids, vitamin E 38
Whole blood Vitamin B1, vitamin, niacin   38
Serum Anti-dengue IgM, anti-dengue IgG   72
Serum C-reactive protein, creatine kinase, lactate dehydrogenase, AST, GGT, lipase, albumin, transferrin Amylase, alanine-amino transferase, alkaline phosphatase 73
Serum MMP-7 TIMP-1, VEGF, VEGF-receptor (unstable after 3 months) 74
Serum Total PSA Free PSA 64
Serum LDL cholesterol, LDL phospholipids, LDL proteins ApoB, cholesterol (VLDL, IDL, HDL), triglycerides (VLDL, IDL, LDL, HDL), phospholipids (VLDL, IDL, HDL), proteins (VLDL, IDL, HDL) 67
Serum Palmitic acid, palmitoleic acid, r-linolenic acid, arachidonic acid, eicosapentaenoic acid, docosahexaenoic acid, saturated fatty acid, mono unsaturated fatty acid, ω 3-polyunsaturated fatty acid Myristic acid, stearic acid, oleic acid, linoleic acid, α-linolenic acid, dihomo-γ-Linolenic acid, docosapentaenoic acid, ω 6-polyunsaturated fatty acid 68
Plasma/Serum C-telopeptides of type I collagen (CTX)   69
Serum   Folate 75
Plasma   Catecholamines (unstable after1 month) 70
Serum   Free PSA 61
Plasma/Serum   Ascorbic acid (unstable after 3 months) 36
Serum   Apolipoprotein E (unstable after 3 months) 66
Plasma   Thromboplastin, prothrombin, thrombin, fibrinogen, coagulation factors II, V, VII, VIII, IX, X, XI, and XII, protein C, protein S, antithrombin, plasminogen, von Willebrand factor, D-dimer (unstable after 3 months) 76

ACTH, adrenocorticotrophic hormone; APTT, activated partial thromboplastin time; FSH, follicle-stimulating hormone; HDL, high density lipoprotein; IDL, intermediate density lipoprotein; LDL, low density lipoprotein; PSA, prostate-specific antigen; PTH, parathyroid hormone; VLDL, very low density lipoprotein.