. 2022 Dec 21;145(1):527–536. doi: 10.1021/jacs.2c10842

Table 4. Catalytic Results of C₆F₅–Alk Couplings Using Alk–Cl and C₆F₅–SnBu₃ Catalyzed by 5^a.

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entry	t (h)	T °C	catalyst	SM	C₆F₅–Alk	C₆F₅–H
1^b	24	70	5 (10%)	32	61	7
2^b	36	70	5 (10%)	0	87	13
3^b	36	90	5 (2%)	21	72	7

SM = starting material.

Substoichiometric AsPh₃ (10 mol % with respect to the Pd catalyst).

Table 4. Catalytic Results of C6F5–Alk Couplings Using Alk–Cl and C6F5–SnBu3 Catalyzed by 5a.