The values of concentrations of MOr, NaBH4 and Ag/Ni-P(NMA-MAa), k0, pH, Ti, Tc and half-life period.
Reaction conditions | pH | MOr (mM) | NaBH4 (mM) | Catalyst (μg mL−1) | T i (min) | T c (min) | k 0 (min−1) | t 1/2 (min) |
---|---|---|---|---|---|---|---|---|
NaBH4 | 5.56 | 0.08 | 7.52 | 85.71 | 5 | 14 | 0.609 | 1.642 |
5.56 | 0.08 | 8.23 | 85.71 | 4 | 11 | 0.706 | 1.416 | |
5.56 | 0.08 | 9.65 | 85.71 | 4 | 9 | 0.915 | 1.093 | |
5.56 | 0.08 | 10.33 | 85.71 | 2 | 6 | 1.083 | 0.923 | |
5.56 | 0.08 | 11.14 | 85.71 | 3 | 8 | 0.925 | 1.081 | |
5.56 | 0.08 | 12.07 | 85.71 | 3 | 10 | 0.782 | 1.279 | |
5.56 | 0.08 | 12.98 | 85.71 | 5 | 12 | 0.694 | 1.441 | |
Catalyst | 5.56 | 0.08 | 9.65 | 54.74 | 5 | 11 | 0.553 | 1.808 |
5.56 | 0.08 | 9.65 | 69.37 | 4 | 9 | 0.72 | 1.389 | |
5.56 | 0.08 | 9.65 | 85.71 | 3 | 7 | 0.892 | 1.121 | |
5.56 | 0.08 | 9.65 | 98.68 | 2 | 5 | 1.006 | 0.994 | |
5.56 | 0.08 | 9.65 | 118.22 | 1 | 4 | 1.152 | 0.868 | |
MeOr | 5.56 | 0.070 | 9.65 | 85.71 | 6 | 13 | 0.596 | 1.678 |
5.56 | 0.075 | 9.65 | 85.71 | 4 | 12 | 0.756 | 1.323 | |
5.56 | 0.080 | 9.65 | 85.71 | 4 | 9 | 1.011 | 0.989 | |
5.56 | 0.085 | 9.65 | 85.71 | 3 | 7 | 1.127 | 0.887 | |
5.56 | 0.090 | 9.65 | 85.71 | 3 | 8 | 0.951 | 1.052 | |
5.56 | 0.095 | 9.65 | 85.71 | 4 | 10 | 0.857 | 1.167 | |
5.56 | 0.100 | 9.65 | 85.71 | 4 | 12 | 0.678 | 1.475 |