Table 3.

Intramolecular Sulfenofunctionalization of Z-Alkenes^a,b,c,def

^aAll reactions performed on a 1.00 mmol scale.

^bYield of isolated, analytically pure product.

^cDiastereomeric ratio determined by ¹H NMR spectroscopic analysis of the crude reaction mixture. Unless otherwise noted, the dr of the products is >99:1.

^dEnantiomeric ratio determined by CSP-HPLC analysis.

^eEnantiomeric ratio determined for major diastereomer.

^fEnantiomeric ratio determined on the corresponding sulfone.