|
a
|
activity [-], |
|
Ao, A1, A2, B, C
|
coefficients in Equations (15) and (49)–(51), A1 and C in K, B in J*mol−1, |
|
∆
|
difference between its solid and liquid heat capacities—and heat capacities, J*(mol*K)−1, |
|
∆
G, GE
|
molar Gibbs free energy and excess Gibbs free energy, J*mol−1, |
|
∆
H, HE
|
molar enthalpy and excess enthalpy, J*mol−1, |
|
l12
|
extended regular solution model binary parameter in S-H Equation (43) [-], |
|
n
|
number of moles, |
|
N
|
amount of data, |
|
P
|
pressure, Pa, |
|
R
|
8.315 J*(mol*K)−1, absolute gas constant, |
|
R2, r2 and
ρ2
|
determinations coefficient of multiple, linear or without intercept [-], |
|
∆
S, SE
|
molar entropy and excess entropy, J*(mol*K)−1, |
|
T
|
absolute temperature, K, |
|
V
|
volume, cm3 mol−1, |
|
Vm
|
mixing volume, cm3 mol−1, |
|
x
|
solute mol fraction [-], |
|
|
constant in Equation (34), K and in Equation (26), Jmol−1, |
|
γ
|
activity coefficient [-], |
|
λ
|
constant in Equation (16) [-], |
|
δ
|
, |
|
Subscripts
|
| 1—solvent, 2—solute, c—compensation, h—harmonic mean, m—melting point, i-th component, j-th component, i ≠ j. |
|
Superscripts
|
|
α, β—phase, o—pure component, sat—saturation, ∅—standard condition, -—average. |