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. 2023 Jan 6;16(2):554. doi: 10.3390/ma16020554

Table 1.

Characteristics and effects of synthetic polymer coatings on Mg-based alloys.

Polymer Polymer Properties Coating Mg-Based Substrate Coating Technology Remarks Ref.
Polylactic Acid (PLA) Biodegradable, Young’s modulus of about 3 GPa, ultimate tensile strength (UTS) of 50–70 MPa, fracture toughness of about 2.5 kJ/m2, biocompatible, degrades through hydrolysis Poly(L-lactic acid) (PLLA) Pure Mg rods Dip-coating PLLA coatings with porous structures and dense surfaces were obtained. The corrosion resistance was improved, and the lower pH of the coating sustained the emission of Mg2+ ions [30]
PLA Mg-9Al-1Zn (AZ91) Spin-coating PLA coating improved the corrosion behavior of the Mg-based alloy [29]
Poly(Lactide-Co-Glycolic) Acid (PLGA) High biocompatibility, already approved for use in human clinical trials, biodegradability, exhibits controllable degradation properties PLGA Mg-6Zn Dip-coating The degradation rate was reduced by a high amount [31]
Polycapro
lactone (PCL)
PCL is Food and Drug Administration (FDA)-approved. Biocompatibiliy, biodegradability, nontoxicity, high strain failure rate PCL Mg-based scaffolds produced through powder metallurgy route Dip-coating The degradation rate was reduced [33]
PCL Mg-6%Zn-10%Ca3(PO4)2 scaffolds Surface sprayed and solidified at 50 °C for 5 min Corrosion activity, surface morphology, and cytotoxicity were improved [32]
Cellulose acetate (CA) It increases corrosion resistance. CA is a thermoplastic material, and its main source is cellulose that is a natural polymer. CA is not manufactured by polymerization of any monomer CA Mg-Ca-Mn-Zr Dip-coating The coating increased the corrosion resistance. The material exhibited good cytocompatibility, promoting cell adhesion, viability, proliferation, and osteogenic differentiation [34]