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. 2023 Jan 3;13(1):60. doi: 10.3390/membranes13010060
a Amount adsorbed at saturation (mol kg−1)
b Langmuir constant (Pa−1)
B Mobility as defined by Equation (11)
C Concentration (mol m−3)
D Diffusivity (m2 s−1)
E Activation energy (kJ mol−1)
J Permeation flux (mol m−2 s−1 Pa−1)
kb Force constant for bond-stretching (kJ mol−1 m−2)
k θ Force constant for angle-bending (kJ mol−1 rad−2)
L Thickness (m)
M Molecular mass (g mol−1)
p Partial pressure (Pa)
Q Partial atomic charge (e)
q Amount of adsorbed (mol kg−1)
r Distance (m)
R Gas constant (=8.314 J K−1 mol−1)
T Temperature (K)
V Diffusion volume (cm3)
Symbols
Γ Thermodynamic factor defined by Equation (14)
δ Kronecker delta (dimensionless)
ε Porosity (dimensionless)
ε 0 Vacuum permittivity (=8.85 × 10−12 F m−1)
Φ Interaction potential energy (kJ mol−1)
ϕ Depth of potential (kJ mol−1)
θ Binding angle (rad)
Θ Surface coverage (dimensionless)
ρ Density of zeolite (kg m−3)
σ Distance at zero-potential energy (m)