Table 1.
No. | 1 a | 2 a | 3 a | 6 b | ||||
---|---|---|---|---|---|---|---|---|
δ C | δ H | δ C | δ H | δ C | δ H | δ C | δ H | |
1 | 166.9, C | 164.5, C | 164.3, C | 166.1, C | ||||
2 | 124.2, C | 120.7, C | 120.3, C | 121.4, C | ||||
3 | 126.3, CH | 7.86, d (7.7) | 126.6, CH | 7.96, dd (7.7, 0.7) | 126.3, CH | 7.88, d (7.7) | 126.8, CH | 8.00, d (7.7) |
4 | 124.2, CH | 7.44, dd (7.7, 7.7) | 124.4, CH | 7.51, dd (7.7, 7.7) | 124.5, CH | 7.49, dd (7.7, 7.7) | 123.9, CH | 7.37, dd (7.7, 7.7) |
5 | 113.7, CH | 7.93, d (7.7) | 115.1, CH | 8.03, dd (7.7, 0.7) | 114.9, CH | 8.03, d (7.7) | 114.6, CH | 7.74, d (7.7) |
6 | 149.2, C | 149.2, C | 149.4, C | 150.1, C | ||||
7 | 140.5, C | 140.8, C | 140.6, C | 141.8, C | ||||
8 | 163.7, C | 164.2, C | 164.3, C | 165.1, C | ||||
9 | 105.6, C | 113.3, C | 105.1, C | 107.1, C | ||||
10 | 139.7, C | 139.5, C | 139.9, C | 140.0, C | ||||
11 | 146.8, C | 147.0, C | 146.8, C | 147.2, C | ||||
12 | 112.5, CH | 7.02, dd (7.7, 0.7) | 112.4, CH | 7.03, d (7.7) | 112.6, CH | 7.03, d (7.7) | 112.1, CH | 6.88, d (7.7) |
13 | 114.9, CH | 6.69, dd (7.7, 8.4) | 114.9, CH | 6.69, dd (7.7, 8.4) | 115.1, CH | 6.69, dd (7.7, 7.4) | 115.4, CH | 6.72, dd (7.7, 7.7) |
14 | 119.5, CH | 7.57, dd (8.4, 1.4) | 119.4, CH | 7.57, dd (8.4, 1.4) | 119.4, CH | 7.57, d (7.7) | 120.3, CH | 7.68, (7.7) |
15 | 55.7, CH3 | 3.87, s | 55.7, CH3 | 3.90, s | 55.7, CH3 | 3.88, s | 55.9, CH3 | 3.94, s |
16 | 66.0, CH2 | 4.39, dd (11.2, 4.2); 4.27, dd (11.2, 5.6) | 65.3, CH2 | 4.56, dd (14.0, 7.0) | 52.4, CH3 | 4.03, s | ||
17 | 69.2, CH | 3.88, m | 34.4, CH2 | 3.14, m | ||||
18 | 62.8, CH2 | 3.53, m | 138.0, C | |||||
19 | 129.0, CH | 7.38, d (7.7) | ||||||
20 | 128.4, CH | 7.31, dd (7.7, 7.7) | ||||||
21 | 126.4, CH | 7.22, dd (7.7, 7.7) | ||||||
22 | 128.4, CH | 7.31, dd (7.7, 7.7) | ||||||
23 | 129.0, CH | 7.38, d (7.7) |
a 700 MHz for 1H, 175 MHz for 13C, DMSO-d6, b 700 MHz for 1H, 175 MHz for 13C, CDCl3, TMS as an internal standard.