Table 1.
Chemical shift, relative intensity of the anomeric (C1) 13C DEPT signals of hydrolyzed EMn (referred to β-galactose), and fractions of α- and β-conformations according to these intensities compared to their tabular values. Percentages (independent of the conformation) of each of the monosaccharides referred to the total amount of monosaccharides.
| Type | 13C C1 (ppm) | Relative Intensity | % Conformation 1 (Tabular Value) | Fraction 2, α and β |
|---|---|---|---|---|
| α-Galp | 92.22 | 0.44 | 31 (32) % | 36% |
| β-Galp | 96.39 | 1.00 | 69 (64) % | |
| α-Xylp | 92.17 | 0.27 | 34 (35) % | 19% |
| β-Xylp | 96.56 | 0.51 | 66 (65) % | |
| α-Manp | 93.97 | 0.20 | 62 (67) % | 8% |
| β-Manp | 93.60 | 0.12 | 38 (33) % | |
| α-Rhap | 93.92 | 0.45 | 55 (60) % | 20% |
| β-Rhap | 93.43 | 0.36 | 45 (40) % | |
| α-Fucp | 92.15 | 0.11 | 33 (21) % | 8% |
| β-Fucp | 96.16 | 0.23 | 67 (67) % |
1 Difference to 100%: furanoses. 2 Difference to 100%: non-assigned signals.