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. 2023 Jan 5;28(2):560. doi: 10.3390/molecules28020560

Table 3.

HPTLC and CE analysis of fruit/berries for analysis of anthocyanins.

No. Identification Technique (Year) Source Extraction Solvent Compounds Activity Ref
1 HPTLC
(2003)
Skin of V. vinifera MeOH-HCl (99.1:0.1) for 16 h agitation at 25 °C Glycosides, acetylglycosides and coumaroylglycosides of 5 (Dp, Mv, Cy, Pn, Pg) main anthocyanins - [57]
2 HPTLC fingerprinting
(2003)
Red fruits and teas (raspberry, straw-berry, blueberry, rose hip, wild berry) acidified ethanol (HCl 0.1% v/v) - - [61]
3 HPTLC
(2012)
Açai berry and supplements Methanol-10% aq. formic acid (9:1) Cy-3-glc, Cy-3-rut - [58]
4 HPTLC-ESI-MS
(2013)
Grape skin, pomace, Grape juice, wine Mv 3-glc, Cy 3-glc, Pn 3-glc, Dp 3-glc, Pg-3-glc and diglc of Mv - [59]
5 HPTLC–Vis–MS
(2014)
bilberry, blueberry, chokeberry, açai berry and cranberry mixture of methanol and hydrochloric acid, 25%, 4:1, v/v Mv 3-glc, Cy 3-glc, Pn 3-glc, Dp 3-glc - [60]
6 HPTLC-UV/Vis and HPTLC-ESI-MS
(2015)
Fresh and dried elderberry Acidified methanol Cy-3-sam and Cy-3-glc - [63]
7 HPTLC
(2015)
cranberry, blueberry, bilberry, chokeberry and açai berry Acidified methanol (4:1) Mv 3-glc, Cy 3-glc, Pn 3-glc, Dp 3-glc Antioxidant activity [62]
8 CE-UV
(2003)
Grapes skin and wine 5% v/v of formic
acid in methanol
My-3, 5-diglc, My-3-glc, My-3-gal, Pg-3-glc, Cy-3, 5-diglc, Cy-3-gal - [66]
9 CE-UV
(2000)
Wild-type blueberry (bilberry) 3% aq.TFA Mv-3-glc, Pn-3-glc, Pt-3-glc, Cy-3-glc, Mv-3-gal, Pt-3-gal, Dp-3-glc, Cy-3-gal, Dp-3-gal, Cy-3-ara, unknown - [67]
10 CE-UV
(2001)
Wild-type blueberry (bilberry) 1% TFA Mv-3-glc, Pn-3-glc, Pt-3-glc, Cy-3-glc, Mv-3-gal, Pt-3-gal, Dp-3-glc, Cy-3-gal, Dp-3-gal, Cy-3-ara, unknown 1-2 - [68]
11 CE-UV
(2004)
Wild-type blueberry (bilberry) 3% aq.TFA Mv-3-glc, Pn-3-glc, Pt-3-glc, Cy-3-glc, Mv-3-gal, Pt-3-gal, Dp-3-glc, Cy-3-gal, Dp-3-gal, Cy-3-ara, Mv-3-ara, Pn-3-ara, Pn-3-gal, Pt-3-ara - [69]
12 CE-UV
(2004)
Wild-type blueberry (bilberry) [1] 100 mM of AAPH at pH 5.6 (0.1 M phosphate buffer)
[2] H2O2 and t-BuOOH
Mv-3-glc, Pn-3-glc, Mv-3-gal, Pt-3-glc, Pn-3-gal, Cy-3-glc, Dp-3-glc, Pt-3-gal, Cy-3-gal, Dp-3-gal, Cy-3-ara, Dp-3-ara - [70]
13 CE-UV
(2004)
Wild-type blueberry (bilberry) 1% aq.TFA Mv-3-glc, Pn-3-glc, Pt-3-glc, Cy-3-glc, Mv-3-gal, Pt-3-gal, Dp-3-glc, Cy-3-gal, Dp-3-gal, Cy-3-ara, Mv-3-ara, Pn-3-ara, Pn-3-gal, Pt-3-ara, Dp-3-ara - [71]
14 CE-UV
(2004)
Cranberry 95% ethanol:1.5 M HCl
85:15 v/v
Pn, Cy - [72]
15 CE-UV/Fluo
(2007)
Grape skin and commercial extracts 0.8% HCl in ethanol–water mixture Mv-3-glc, Pn-3-glc, Cn-3-glc, Dp-3-glc - [73]
16 CE-UV
(2008)
Strawberries (cv. Camarosa) acidified water (3% formic acid) Pg-3-glu, Pg-3-rut and Cy-3-glc - [74]