Table 2. NMR Data for Tuaimenals C, D, E, F, G, and H (2–7)a.
| tuaimenal
C |
tuaimenal
D |
tuaimenal
E |
tuaimenal
F |
tuaimenal
G |
tuaimenal
H |
|||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| pos | δC,b type | δHc (J in Hz) | δC,b type | δHc (J in Hz) | δC,b type | δHc (J in Hz) | δC,b type | δHc (J in Hz) | δC,b type | δHc (J in Hz) | δC,b type | δHc (J in Hz) |
| 1 | 143.7, C | 138.6, C | 132.2, C | 139.5, C | 147.3, C | 134.2, C | ||||||
| 2 | 142.4, C | 151.4, C | 151.4, C | 147.3, C | 139.6, C | 152.5, C | ||||||
| 3 | 124.5, C | 111.8, C | 111.8, C | 118.2, C | 118.1, C | 109.6, C | ||||||
| 4 | 114.4, CH | 6.45, s | 158.2, C | 158.2, C | 107.5, CH | 6.25, s | 107.5, CH | 6.26, s | 159.5, C | |||
| 5 | 146.7, C | 107.6, C | 107.6, C | 146.7, C | 146.7, C | 110.7, C | ||||||
| 6 | 119.9, C | 118.6, C | 118.7, C | 119.8, C | 119.8, C | 126.9, C | ||||||
| 7 | 122.5, CH | 6.27, d (9.8) | 116.5, CH | 6.87, d (10.2) | 116.5, CH | 6.86, d (10.2) | 122.6, CH | 6.24, ov d | 122.6, CH | 6.25, d, (9.8) | 23.5, CH2 | 3.60, br s |
| 8 | 129.6, CH | 5.57, d (9.8) | 132.4, CH | 5.80, d (9.8) | 132.4, CH | 5.80, d (10.2) | 129.7, CH | 5.56, d (9.8) | 129.7, CH | 5.57, d (9.8) | 121.1, CH | 5.16, br t |
| 9 | 79.0, C | 79.2, C | 79.1, C | 78.1, C | 78.1, C | 139.2, C | ||||||
| 10 | 41.6, CH2 | 1.84, m | 40.3, CH2 | 1.77, m | 40.3, CH2 | 1.78, m | 41.2, CH2 | 1.83, m | 41.2, CH2 | 1.83, m | 39.5, CH2 | 2.08, m |
| 1.67, m | 1.67, m | 1.68, m | ||||||||||
| 11 | 23.0, CH2 | 2.18, m | 22.5, CH2 | 1.43, m | 22.6, CH2 | 2.11, m | 22.8, CH2 | 2.15, m | 22.8, CH2 | 2.16, m | 26.2, CH2 | 2.11, m |
| 2.12, m | ||||||||||||
| 12 | 124.0, CH | 5.13, t (6.47) | 123.6, CH | 5.12, t (7.08) | 123.6, CH | 5.11, t (6.99) | 124.2, CH | 5.14, t (7.08) | 124.2, CH | 5.13, t (6.9) | 123.3, CH | 5.04, t (6.36) |
| 13 | 135.6, C | 135.8, C | 135.6, C | 135.2, C | 135.1, C | 135.9, C | ||||||
| 14 | 39.8, CH2 | 1.97, t | 39.9, CH2 | 1.97, t (6.18) | 39.7, CH2 | 1.96, m | 39.9, CH2 | 1.96, t (6.54) | 39.7, CH2 | 1.95, t (7.63) | 39.6, CH2 | 1.96, t (7.63) |
| 15 | 26.8, CH2 | 2.06, m | 22.6, CH2 | 2.13, m | 22.0, CH2 | 1.68, m | 22.6, CH2 | 1.44, m | 22.1, CH2 | 1.40, m | 26.6, CH2 | 2.03, m |
| 1.38, m | ||||||||||||
| 16 | 124.4, CH | 5.09, t (6.96) | 43.4, CH2 | 1.43, m | 40.2, CH2 | 1.69, m | 43.3, CH2 | 1.42, m | 40.4, CH2 | 1.67, m | 124.2, CH | 5.07, t (6.72) |
| 17 | 131.5, C | 70.1, C | 82.4, C | 71.1, C | 82.4, C | 131.4, C | ||||||
| 18 | 17.8, CH3 | 1.60, s | 29.2, CH3 | 1.22, s | 26.1, CH3 | 1.42, s | 29.2, CH3 | 1.21, s | 26.0, CH3 | 1.42, s | 17.6, CH3 | 1.60, s |
| 19 | 25.8, CH3 | 1.68, s | 29.2, CH3 | 1.22, s | 26.1, CH3 | 1.42, s | 29.2, CH3 | 1.21, s | 26.0, CH3 | 1.42, s | 25.7, CH3 | 1.67, s |
| 20 | 16.1, CH3 | 1.59, s | 15.9, CH3 | 1.58, s | 15.8, CH3 | 1.57, s | 15.8, CH3 | 1.57, s | 15.8, CH3 | 1.57, s | 16.0, CH3 | 1.59, s |
| 21 | 26.5, CH3 | 1.41, s | 25.4, CH3 | 1.43, s | 25.4, CH3 | 1.43, s | 25.9, CH3 | 1.39, s | 25.9, CH3 | 1.39, s | 16.4, CH3 | 1.82, s |
| 22 | 9.9, CH3 | 2.05, s | 7.6, CH3 | 2.14, s | 7.6, CH3 | 2.14, s | 9.0, CH3 | 2.14, s | 9.0, CH3 | 2.14, s | 7.3, CH3 | 2.12, s |
| 23 | 60.5, CH3 | 3.84, s | 191.1, CH | 10.09, s | 191.0, CH | 10.08, s | 60.4, CH3 | 3.83, s | 60.4, CH3 | 3.84, s | 192.9, CH | 9.98, s |
| 24 | 169.8, C | 170.5, C | 170.6, C | |||||||||
| 25 | 20.9, CH3 | 2.30, s | 22.5, CH3 | 1.97, s | 22.5, CH3 | 1.97, s | ||||||
a
CDCl3, ppm.
b
150 MHz, type established by phase-sensitive HSQC.
c
600 MHz.