Table 3. Selected Distances (Å) and Angles (°) for Binuclear Complexes 7–9.
| parameter | 7 | 8 | 9 |
|---|---|---|---|
| Pt(1)–CC^N | 2.008(4) | 2.008(3) | 1.947(2) |
| Pt(1)–N(1) | 2.116(3) | 2.038(2) | 2.0760(19) |
| Pt(1)–Ccyanide | 2.029(3) | 2.016(2) | 1.9586 (19) |
| Pt(1)–Ctol | 2.017(3) | 1.949(2) | 1.996(2) |
| C≡N | 1.152(4) | 1.144(3) | 1.111(3) |
| Pt(2)–CC^N′ | 2.016(4) | 2.007(3) | 1.948(2) |
| Pt(2)–N(3) | 2.108(3) | 2.038(2) | 2.0794(19) |
| Pt(2)–N(2) | 2.029(3) | 2.021(2) | 1.960(2) |
| Pt(2)–Ctol′ | 2.018(4) | 1.948(2) | 1.997(2) |
| CC^N-Pt(1)–N(1) | 81.26(13) | 79.28(10) | 81.91(9) |
| CC^N′-Pt(2)–N(3) | 80.90(15) | 79.25(10) | 81.93(9) |
| Pt(1)–Ccyanide–N(2)–Pt(2) | 42.74 | 33.18 | 12.39 |