Table 2.
Results of the microbial oxidation of syn-3-methyloctane-1,4-diol (1b) in MTPs.
Strain | Time [hours] | Conv. 1b [%] | Products | |||
---|---|---|---|---|---|---|
Trans [%] | ee [%] | Cis [%] | ee [%] | |||
Dietzia sp. DSM44016 | 6 | 0 | – | – | – | – |
24 | 78 (±2.2) | 15 (±1.0) | 99 (+) | 63 (±1.3) | 64 (+) | |
48 | 100 | 23 (±0.4) | 98 (+) | 77 (±1.5) | 97 (+) | |
Gordonia bronchialis PCM2167 | 6 | 0 | – | – | – | – |
24 | 79 (±1.5) | 35 (±0.8) | 62 (+) | 44 (±0.5) | 73 (+) | |
48 | 100 | 45 (±1.5) | 87 (+) | 55 (±1.2) | 92 (+) | |
Gordonia rubripertincta PCM2144 | 6 | 0 | – | – | – | – |
24 | 50 (±0.9) | 31 (±1.1) | 5 (+) | 19 (±0.4) | 13 (+) | |
48 | 74 (±1.5) | 63 (±0.7) | 58 (+) | 11 (±1.1) | 41 (+) | |
Micrococcus luteus PCM525 | 6 | 0 | – | – | – | – |
24 | 85 (±2.1) | – | – | 85 (±1.2) | 70 (−) | |
48 | 100 | – | – | 100 (±0.0) | 20 (−) | |
Rhodococcus coprophilus PCM2174 | 6 | 0 | – | – | – | – |
24 | 43 (±0.9) | 24 (±1.1) | 33 (+) | 19 (±0.8) | 17 (+) | |
48 | 90 (±1.1) | 47 (±2.1) | 23 (+) | 43 (±1.7) | 7 (+) | |
Rhodococcus erythropolis DSM44534 | 6 | 40 (±1.1) | – | – | 40 (±0.4) | 90 (+) |
24 | 100 | – | – | 100 | 99 (+) | |
48 | 100 | – | – | 100 | 99 (+) | |
Rhodococcus erythropolis PCM2150 | 6 | 11 (±0.2) | 4 (±0.2) | – | 7 | – |
24 | 100 | 26 (±1.2) | 99 (+) | 74 (±1.5) | 99 (+) | |
48 | 100 | 11 (±0.9) | 74 (+) | 89 (±0.7) | 99 (+) | |
Rhodococcus ruber PCM2166 | 6 | 0 | – | – | – | – |
24 | 40 (±0.8) | – | – | 40 (±0.9) | 73 (+) | |
48 | 89 (±1.3) | 14 (±0.8) | 98 (+) | 75 (±1.0) | 82 (+) | |
Rhodococcus ruber PCM2171 | 6 | 0 | – | – | – | – |
24 | 32 (±0.4) | 17 (±0.6) | – | 15 (±0.8) | – | |
48 | 80 (±1.5) | 51 (±1.4) | 19 (+) | 29 (±1.1) | 22 (+) | |
Rhodococcus rhodnii PCM2157 | 6 | 0 | – | – | – | – |
24 | 52 (±2.0) | – | – | 52 (±2.3) | 67 (+) | |
48 | 87 (±0.9) | – | – | 87 (±1.9) | 77 (+) | |
Rhodococcus rhodochrous PCM909 | 6 | 0 | – | – | – | – |
24 | 60 (±1.7) | 41 (±0.8) | 35 (+) | 19 (±0.3) | 59 (+) | |
48 | 100 | 63 (±1.2) | 44 (+) | 37 (±0.7) | 63 (+) | |
Streptomyces griseus subsp. griseus PCM2331 | 6 | 0 | – | – | – | – |
24 | 20 (±0.4) | 8 (±0.2) | – | 12 (±0.7) | 10 (+) | |
48 | 60 (±1.3) | 23 (±0.8) | – | 37 (±1.2) | 9 (+) |
%, determined by CGC.