Table 3.
Results of the biotransformation of anti-3-methyloctane-1,4-diol (1a).
| Strain | Time [hours] | Conv. 1a [%] | Products | |||
|---|---|---|---|---|---|---|
| Trans [%] | ee [%] | Cis [%] | ee [%] | |||
| Dietzia sp. DSM44016 | 6 | 2 (±0.3) | - | - | 2 (±0.1) | 50 (+) |
| 24 | 25 (±1.3) | 24 (±0.9) | 92 (+) | 1 (±0.1) | 99 (+) | |
| 48 | 100 | 95 (±1.0) | 40 (+) | 5 (±0.7) | 99 (+) | |
| 72 | 100 | 87 (±1.2) | 54 (−) | 13 (±0.9) | 99 (+) | |
| Rhodococcus erythropolis DSM44534 | 6 | 33 (±1.0) | 29 (±0.8) | 62 (+) | 4 (±0.4) | 99 (+) |
| 24 | 100 | 87 (±1.1) | 30 (−) | 13 (±0.7) | 99 (+) | |
| 48 | 100 | 82 (±1.3) | 99 (−) | 18 (±0.5) | 99 (+) | |
| 72 | 100 | 100 | 99 (−) | - | - | |
| Rhodococcus erythropolis PCM2150 | 6 | 100 | 96 (±1.0) | 0 | 4 (±0.7) | 99 (+) |
| 24 | 100 | 47 (±0.3) | 88 (−) | 53 (±1.2) | 99 (+) | |
| 48 | 100 | 25 (±1.1) | 99 (−) | 75 (±1.8) | 99 (+) | |
| 72 | 100 | 22 (±0.6) | 99 (−) | 78 (±1.1) | 99 (+) | |
| Rhodococcus ruber PCM2166 | 6 | 0 | - | - | - | - |
| 24 | 13 (±0.3) | 11 (±0.9) | 70 (+) | 2 (±0.2) | 40 (+) | |
| 48 | 38 (±0.7) | 34 (±0.5) | 64 (+) | 4 (±0.7) | 75 (+) | |
| 72 | 69 (±1.4) | 58 (±1.6) | 64 (+) | 11 (±0.5) | 72 (+) | |
%, determined by CGC.