Figure 3.

Workflow for the noniterative generation of focused libraries in the Chemputer. (Left) A library in chemical space of Ru(bipy)₂Cl₂ derivatives. (Right) A library in process space of reaction compositions leading to the formation of polyoxomolybdates. In each case, the reagents, synthetic procedure, library construction, methods of analysis, and isolated products are shown. Polyoxomolybdate polyhedra are colored according to the structural building blocks represented: {Mo{Mo₅}}, cyan and blue; {Mo₁}, yellow; {Mo₂} in red. Note that {Mo₂} building blocks in {Mo₁₃₂} are formed from edge-sharing octahedral, and corner-sharing in {Mo₁₅₄}.