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The number of species (Li+, EC, EMC, FEC, and PF6–) in the EDL for the carbonate-based electrolytes, (a) LiPF6@EC:EMC and (b) LiPF6@EC:EMC:FEC at 20 °C. The number of species (Li+, TFSI–, FEC, DOL, and DME) in the EDL for the ether-based electrolytes, (c) LiTFSI@DOL:DME and (d) LiTFSI@DOL:DME:FEC at 20 °C as well as (e) LiTFSI@DOL:DME and (f) LiTFSI@DOL:DME:FEC at −40 °C.
