Table 3.
Use of co-solvents in homogeneous acidic catalysed methanolysis.
| Co- solvent |
Catalyst | Reactor type | Feedstock | Pre- treatment |
Reaction conditions |
Yield (wt.%e) |
Ref. | ||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Co-solvent amount (wt.%a,b, v.%c, mol%d) |
Catalyst amount (wt.%a) | MeOH/oil molar ratio | Time (min) |
T (°C) |
Stirrer (rpm) |
Special conditions |
|||||||
| DME | PTSA | Oscillated vial | Corn oil | – | 176 v.% | 4 | 10:01 | 120 | 80 | shaking 2.6 Hz |
500 kPa | 97.1 | [64] |
| MTBE | H2SO4 | STR | PFAD | – | 39 v.% (25 wt%a) |
10 | 7:1 | 70 | 55 | 300 | – | 96.80 | [65] |
| n-hexane | H2SO4 | STR | BSFL powder | 1 | 50 v.% | 1.2 ml | 12 ml MeOH | 90 | 120 | N/S | – | 94.14 | [66] |
|
Jatropha curcas L. seeds |
2 | 10 v.% | 15 | 7.5 ml/g | 24 h | 60 | 99.80 | [67] | |||||
| THF | AlCl3 | STR | Canola oil | – | 90 v.% (100 wt%b) |
5 | 24:1 | 18 h | 110 | N/S | – | 98f | [68] |
| H2SO4 | Vial |
Chlorella vulgaris microalgae lipid |
50 v.% (25 mol%) |
21 | 60:1 | 180 | 60 | -g | 95 | [69] | |||
| Oscillated flask | Coconut meat | 2 | 40 v.% | 25% (v/wt.) | 60:1 | N/S | 60 | shaking | 96.7 | [70] | |||
Reduction in particle size.
1. (<0.25 mm).
2. (<0.355 mm).
regarding the oil weight.
regarding methanol weight.
regarding the MeOH volume.
regarding mole MeOH.
%FAME yield.
% oil conversion.
no agitation.