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. 2023 Jan 18;9(1):e13006. doi: 10.1016/j.heliyon.2023.e13006

Table 3.

Use of co-solvents in homogeneous acidic catalysed methanolysis.

Co-
solvent
Catalyst Reactor type Feedstock Pre-
treatment
Reaction conditions

Yield
(wt.%e)
Ref.
Co-solvent amount
(wt.%a,b, v.%c, mol%d)
Catalyst amount (wt.%a) MeOH/oil molar ratio Time
(min)
T
(°C)
Stirrer
(rpm)
Special
conditions
DME PTSA Oscillated vial Corn oil 176 v.% 4 10:01 120 80 shaking
2.6 Hz
500 kPa 97.1 [64]
MTBE H2SO4 STR PFAD 39 v.%
(25 wt%a)
10 7:1 70 55 300 96.80 [65]
n-hexane H2SO4 STR BSFL powder 1 50 v.% 1.2 ml 12 ml MeOH 90 120 N/S 94.14 [66]
Jatropha curcas
L. seeds
2 10 v.% 15 7.5 ml/g 24 h 60 99.80 [67]
THF AlCl3 STR Canola oil 90 v.%
(100 wt%b)
5 24:1 18 h 110 N/S 98f [68]
H2SO4 Vial Chlorella vulgaris
microalgae lipid
50 v.%
(25 mol%)
21 60:1 180 60 -g 95 [69]
Oscillated flask Coconut meat 2 40 v.% 25% (v/wt.) 60:1 N/S 60 shaking 96.7 [70]

Reduction in particle size.

1. (<0.25 mm).

2. (<0.355 mm).

a

regarding the oil weight.

b

regarding methanol weight.

c

regarding the MeOH volume.

d

regarding mole MeOH.

e

%FAME yield.

f

% oil conversion.

g

no agitation.