M = Mg | Hydrometallation | β-Alkyl migration | ||
---|---|---|---|---|
N | TS-1 | 4a–d | TS-2 | 6a–d |
1 | 21.7 | −24.7 | 19.0 | −3.1 |
2 | 24.0 | −15.6 | 28.0 | −0.5 |
3 | 22.4 | −14.8 | 40.7 | 19.0 |
4 | 22.2 | −15.5 | 53.6 | 23.4 |
M = Mg | Hydrometallation | β-Alkyl migration | ||
---|---|---|---|---|
N | TS-1 | 4a–d | TS-2 | 6a–d |
1 | 21.7 | −24.7 | 19.0 | −3.1 |
2 | 24.0 | −15.6 | 28.0 | −0.5 |
3 | 22.4 | −14.8 | 40.7 | 19.0 |
4 | 22.2 | −15.5 | 53.6 | 23.4 |