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. 2023 Jan 23;16(3):1024. doi: 10.3390/ma16031024

Table 1.

Comparison of the performance of different analytical methods in the quantification of BTL.

Analytical Method Tools Matrix LOD/nmol L−1 Ref.
Chromatographic HPLC-UV with SPME a Surface water 0.2 [38]
Chromatographic HPLC-UV-ESI/MS b Tobacco leaf powder 508 [39]
Immunochromatographic Gold-based strip sensor Phosphate buffer saline (pH 7.4) 10.4 [20]
Electrochemical Co-Ag BMNPs-PVP/GCE c B–R buffer (pH 2.0) 32.0 [17]
Electrochemical Dropping mercury electrode B–R buffer (pH 4.0) 60.0 [22]
Electrochemical PBA-qnz/CPE B–R buffer (pH 2.0) 170 This study

a HPLC-UV with SPME—High-performance liquid chromatography with ultraviolet detection with solid phase microextraction fiber coating based on silicone sealant/hollow ZnO@CeO2 composite; b HPLC-UV-ESI/MS—High-performance liquid chromatography with ultraviolet detection and electrospray ionization mass spectrometry; c Co-Ag BMNPs-PVP/GCE—Glassy carbon electrode modified with Co and Ag bimetallic nanoparticles immobilized in poly(vinylpyrrolidone).