Table 2.
Experimental data for the determination of spectra reported in Figure 4. The V1b and VPQ volumes refer to an initial 1b solution with a concentration of 50.7 μg L−1 and paraquat, PQ, solution with a concentration of 1000 μg L−1, respectively. The final volume of each solution was made up to a total volume of 4000 μL by fixing with the solvent mixture.
Entry | V1b, μL | VPQ, μL | VTOT, μL | [1b], μg L−1 | [PQ], μg L−1 | PQ/1b, mol/mol |
---|---|---|---|---|---|---|
1 | 2000 | 0 | 4000 | 25.4 | 0.0 | 0.0 |
2 | 2000 | 3 | 4000 | 25.4 | 0.8 | 0.1 |
3 | 2000 | 6 | 4000 | 25.4 | 1.5 | 0.3 |
4 | 2000 | 9 | 4000 | 25.4 | 2.3 | 0.4 |
5 | 2000 | 12 | 4000 | 25.4 | 3.0 | 0.6 |
6 | 2000 | 16 | 4000 | 25.4 | 4.0 | 0.8 |
7 | 2000 | 20 | 4000 | 25.4 | 5.0 | 0.9 |
8 | 2000 | 25 | 4000 | 25.4 | 6.3 | 1.2 |
9 | 2000 | 32 | 4000 | 25.4 | 8.0 | 1.5 |
10 | 2000 | 40 | 4000 | 25.4 | 10.0 | 1.9 |
11 | 2000 | 50 | 4000 | 25.4 | 12.5 | 2.4 |
12 | 2000 | 60 | 4000 | 25.4 | 15.0 | 2.8 |
13 | 2000 | 75 | 4000 | 25.4 | 18.8 | 3.5 |
14 | 2000 | 90 | 4000 | 25.4 | 22.5 | 4.3 |
15 | 2000 | 110 | 4000 | 25.4 | 27.5 | 5.2 |
16 | 2000 | 135 | 4000 | 25.4 | 33.8 | 6.4 |
17 | 2000 | 155 | 4000 | 25.4 | 38.8 | 7.3 |
18 | 2000 | 185 | 4000 | 25.4 | 46.3 | 8.7 |
19 | 2000 | 225 | 4000 | 25.4 | 56.3 | 10.6 |
20 | 2000 | 285 | 4000 | 25.4 | 71.3 | 13.5 |
21 | 2000 | 365 | 4000 | 25.4 | 91.3 | 17.3 |
22 | 2000 | 464 | 4000 | 25.4 | 116.0 | 21.9 |
23 | 2000 | 650 | 4000 | 25.4 | 162.5 | 30.7 |
24 | 2000 | 800 | 4000 | 25.4 | 200.0 | 37.8 |
25 | 2000 | 1000 | 4000 | 25.4 | 250.0 | 47.3 |