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. 2023 Feb 1;28(3):1385. doi: 10.3390/molecules28031385

Table 3.

Redox potentials of corroles 14 in dry DCM solution (E versus SHE).

Corrole Eox1 Eox2 Eox3 Ered1 EHOMO d ELUMO e ΔE
1 * +0.65 V a +0.78 V c +0.95 V c −1.29 V b −5.45 −3.51 1.94
2 +0.80 V a +1.32 V c - −1.18 V b −5.60 −3.62 1.98
3 +0.60 V a +1.09 V c +1.93 V c −1.21 V b −5.40 −3.59 1.81
4 +0.21 V a +0.95 V c +1.62 V c −1.37 V b −5.01 −3.43 1.58

a Anodic peak = Epa; b Cathodic peak = Epc; c E1/2 = Epa + Epc/2; d EHOMO = −[4.8 + Eox1 (versus SHE]eV; e ELUMO = −[4.8 + Ered1 (versus SHE]eV; * Ref. [5].