Table 5.

Identities and results from the analysis of representative case samples. Samples originated from powders unless otherwise noted. Standard retention times and MS match scores are provided for the synthetic opioids and related compounds only. MS match scores were obtained by searching against the SWGDRUG Library (v3.6).

Case Contents	Sample RT (min)	Standard RT (min)	%RTD (relative to standard)	MS Match Score (Weighted)	Opioid Peak Height (Count/s)
N-methyl Norfentanyl	2.453	2.470	0.69 %	98	1.5×107
Mannitol Caffeine Heroin Cyclopropyl Fentanyl Phenyl Fentanyl	2.196 2.427 9.207 9.740 17.811	9.214 9.767 18.022	0.08 % 0.28 % 1.17 %	99 97 95	5.8×106 1.0×106 1.1×105 6.4×105 1.4×105
Mannitol Fentanyl Acetyl Fentanyl Melatonin	2.383 8.755 8.906 11.394	8.847 8.941	1.04 % 0.39 %	97 94	3.4×106 2.7×106 1.6×106 1.1×106
Mannitol Caffeine 6-Monoacetylmorphine FIBF Fentanyl Acetyl Fentanyl Heroin	2.220 2.424 6.556 8.544 8.748 8.899 9.243	6.559 8.580 8.847 8.941 9.214	0.05 % 0.42 % 1.12 % 0.47 % 0.31 %	98 97 97 94 98	4.5×106 2.5×107 3.7×106 2.9×106 1.0×106 4.7×106 1.1×107
Fentanyl XLR11 XLR Degradant	8.707 9.476 10.216	8.847	1.58 %	97	1.5×106 1.2×107 7.3×105
Dibutylone Fentanyl JWH-250	1.893 8.724 15.188	8.847	1.39 %	97	2.5×105 3.4×105 5.3×106
AP-238	5.454	5.420	0.63 %	97*	1.7×107
Phenacetin Mannitol Xylazine Caffeine Lidocaine 6-Monoacetylmorphine Fentanyl	2.082 2.150 2.350 2.412 2.824 6.527 8.689	6.559 8.847	0.49 % 1.78 %	89 97	7.9×104 6.2×105 8.7×104 8.4×106 4.4×104 3.9×104 4.2×104
Mannitol Caffeine Cocaine Acetylcodeine 6-Monoacetylmorphine FIBF Fentanyl Acetyl Fentanyl Heroin Noscapine	2.144 2.412 3.624 6.061 6.527 8.526 8.695 8.858 9.202 21.150	6.559 8.580 8.847 8.941 9.214 21.224	0.49 % 0.63 % 1.72 % 0.92 % 0.13 % 0.35 %	98 98 97 94 98 96	4.5×105 9.4×106 3.7×104 1.6×105 3.9×105 3.5×105 6.6×105 2.4×105 5.0×106 4.0×104
N-methyl Cyclopropyl norfentanyl	2.662	2.714	1.91 %	97	2.4×106

^*AP-238 is not in the SWGDRUG Library v3.6. Comparison score was obtained using v3.9.