Table 4. Selected Bond Lengths and Angles from Compound 6.
| bond lengths (Å) | |||
|---|---|---|---|
| Li(1)–O(1) | 1.962(3) | Li(3)–O(1) | 1.845(3) |
| Li(1)–O(4) | 1.951(2) | Li(3)–O(31) | 1.912(6) |
| Li(2)–O(1) | 1.952(4) | B(1)–O(1) | 1.682(2) |
| Li(2)–O(3) | 2.078(4) | B(1)–O(2) | 1.360(3) |
| Li(2)–O(4)# | 1.863(4) | B(1)–O(3) | 1.479(2) |
| Li(2)–O(41) | 1.962(4) | B(1)–N(1) | 1.499(2) |
| bond angles (deg) | |||
|---|---|---|---|
| O(1)–Li(1)–O(1)# | 96.8(2) | O(3)–B(1)–N(1) | 104.23(15) |
| O(1)–Li(1)–O(4) | 120.95(8) | Li(1)–O(1)–Li(2) | 83.44(13) |
| O(1)–Li(1)–O(4)# | 93.66(6) | Li(1)–O(1)–Li(3) | 78.90(17) |
| O(4)–Li(1)–O(4)# | 128.4(3) | Li(1)–O(1)–B(1) | 130.22(15) |
| O(1)–Li(2)–O(3) | 71.60(12) | Li(2)–O(1)–Li(3) | 119.70(13) |
| O(1)–Li(2)–O(4) | 96.80(16) | Li(2)–O(1)–B(1) | 92.99(15) |
| O(1)–Li(2)–O(41) | 122.2(2) | Li(3)–O(1)–B(1) | 140.39(16) |
| O(3)–Li(2)–O(4)# | 129.68(19) | Li(2)–O(3)–B(1) | 84.22(14) |
| O(1)–Li(3)–O(1)# | 105.4(3) | Li(2)–O(3)–C(10) | 148.01(16) |
| O(1)–Li(3)–O(31) | 127.32(13) | B(1)–O(3)–C(10) | 121.89(15) |
| O(1)–B(1)–O(2) | 118.05(17) | Li(1)–O(4)–Li(2)# | 86.10(14) |
| O(1)–B(1)–N(1) | 111.29(15) | Li(1)–O(4)–C(19) | 136.29(13) |
| O(2)–B(1)–N(1) | 104.06(14) | Li(2)#–O(4)–C(19) | 134.36(16) |