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. 2022 Oct 21;22(11):6504–6520. doi: 10.1021/acs.cgd.2c00722

Table 2. Crystallographic Data for PRM-4AP, PRM-4DMP, PRM-PPZ, MEL-4AP, MEL-4DMP, and MEL-PPZ Salts.

  PRM-4AP 1:1 PRM-4DMP 1:1 PRM-PPZ 1:0.5 MEL-4AP 1:1 MEL-4DMP 1:1 MEL-PPZ 1:0.5
chemical formula C20H19N5O4S C22H23N5O4S C17H18N4O4S C19H19N5O4S2 C21H23N5O4S2 C16H18N4O4S2
formula weight 425.46 453.52 374.41 445.51 473.56 394.46
crystal system triclinic monoclinic monoclinic monoclinic triclinic monoclinic
space group P C2/c P21/c Cc P P21/c
temperature (K) 293(2) 296 299(2) 296 298(2) 298(2)
a (Å) 8.2328(12) 22.431(3) 9.944(4) 11.813(2) 8.3482(7) 8.002(4)
b (Å) 10.6200(16) 16.048(3) 7.906(3) 20.427(4) 10.4251(15) 29.90(2)
c (Å) 12.361(4) 12.900(2) 22.650(12) 10.2167(17) 12.6635(7) 7.512(4)
α (°) 75.393(16) 90 90 90 90.789(7) 90
β (°) 71.368(12) 109.888(6) 96.56(2) 123.016(3) 95.355(5) 106.380(18)
γ (°) 89.872(10) 90 90 90 95.567(7) 90
volume (Å3) 987.4(4) 4366.7(13) 1769.1(13) 2067.1(6) 1091.84(19) 1724.6(18)
Z 2 8 4 4 2 4
ρcalc (g cm–3) 1.431 1.380 1.406 1.432 1.444 1.519
radiation type Cu Kα Mo Kα Mo Kα Mo Kα Cu Kα Mo Kα
μ (mm–1) 1.795 0.188 0.214 0.295 2.551 0.340
reflns measured 40074 27903 57483 7186 57119 76271
reflns independent 3809 5504 9923 3309 4267 6931
significant [I > 2σ(I)] 3670 4248 7423 3236 4010 3067
parameters refined 272 292 235 273 290 235
restraints 0 6 0 26 0 0
Δρmax, Δρmin (e Å–3) 0.367, −0.465 0.381, −0.451 0.404, −0.417 0.140, −0.232 0.331, −0.559 0.385, −0.445
F(000) 444 1904 784 928 498 824
R1 [I > 2σ(I)] 0.0435 0.0561 0.0425 0.0260 0.0344 0.0609
wR2 (all data) 0.1193 0.1200 0.1338 0.0654 0.1017 0.1916
CCDC number 2064483 2109805 2064485 2109802 2109803 2109804