Table 5. Comparison of the Maximum Fluorescence Emission Wavelengths, Fluorescence Quantum Yields, and Contributions of π–π and Hydrogen Bonding of PRM, PRM-4AP, PRM-4DMP, and PRM-PPZ.
λemmax (nm) | ΦFa | π–πb(%) | hydrogen bondingb(%) | |
---|---|---|---|---|
PRM | 460 | 0.614 | 6.2 | 33.8 |
PRM-4AP | 477 | 0.685 | 5.1 | 33.9 |
PRM-4DMP | 471 | 0.660 | 2.2 | 33.7 |
PRM-PPZ | 463 | 0.408 | 2.3 | 32.7 |
Fluorescence quantum yields excited at 365 nm.
Refers to the contribution of π–π interactions and hydrogen bonding in the crystal structures. Values are those obtained from Hirshfeld surface calculations (Table S4).