Demethylation of compounds derived from oxidative depolymerization of lignina.
| Entry | Substrate | Product | Conversion (%) | Yield (%) |
|---|---|---|---|---|
| 1 |
|
|
96 | 92 |
| 100b | 87b | |||
| 2 |
|
|
100 | 97 |
| 3 |
|
|
99 | 87 |
| 100b | 54b | |||
| 4 |
|
|
100 | 36 |
| 5 |
|
|
98 | 50 |
| 100b | 31b | |||
| 6 |
|
|
100 | 32 |
Conditions: 0.1 mmol substrate, 2.5 mL, 61.7% LiBr with 1.5 M HCl, 110 °C, and 1 h.
Time, 2 h.