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. 2023 Feb 17;13(9):5925–5932. doi: 10.1039/d3ra00245d

Demethylation of compounds derived from oxidative depolymerization of lignina.

Entry Substrate Product Conversion (%) Yield (%)
1 graphic file with name d3ra00245d-u1.jpg graphic file with name d3ra00245d-u2.jpg 96 92
100b 87b
2 graphic file with name d3ra00245d-u3.jpg graphic file with name d3ra00245d-u4.jpg 100 97
3 graphic file with name d3ra00245d-u5.jpg graphic file with name d3ra00245d-u6.jpg 99 87
100b 54b
4 graphic file with name d3ra00245d-u7.jpg graphic file with name d3ra00245d-u8.jpg 100 36
5 graphic file with name d3ra00245d-u9.jpg graphic file with name d3ra00245d-u10.jpg 98 50
100b 31b
6 graphic file with name d3ra00245d-u11.jpg graphic file with name d3ra00245d-u12.jpg 100 32
a

Conditions: 0.1 mmol substrate, 2.5 mL, 61.7% LiBr with 1.5 M HCl, 110 °C, and 1 h.

b

Time, 2 h.