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. 2023 Feb 3;10:960894. doi: 10.3389/fchem.2022.960894

TABLE 4.

Temperature-dependent pyrolysis reactions (Bilitewski et al., 1997).

Chemical reaction Temperature range
Dehydration, thermal drying 100–120
Desulfurization, deoxidation, CO2 and H2O molecular splitting, H2S splitting 250
Aliphatic hydrocarbon bonds breakage, methane and other aliphatic hydrocarbons splitting 340
Carbonization 380
C-O and C-N bonds breakage 400
Bituminous (asphalt) compounds disintegration into low temperature tars and oils 400–600
Bituminous (asphalt) compounds cracking into thermal resistant elements, aromatic organic compounds formation 600
Thermal aromatization of ethene to hexanaphthene to C6H6 formation and other volatile aromatic hydrocarbons >600