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. 2023 Feb 4;145(6):3786–3794. doi: 10.1021/jacs.2c13318

Figure 1.

Figure 1

Metallomimetic chemistry of geometrically constrained PIII species. Previously reported stepwise, noncatalytic hydrodefluorination of fluoroarenes (top); this work, catalytic hydrodefluorination and amination of fluoroarenes (bottom).