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. 2023 Feb 3;25(6):987–991. doi: 10.1021/acs.orglett.3c00074

Table 1. Yields of Isolated Piperazines 2.

Entry X R1 R2 Product Yield (%)
1 Br H COMe 2a 80
2 Br H CO2tBu 2b 55
3 Br H F 2c 30
4 Br H CF3 2d 34
5 Br H CN 2e 70
6 Br H Cl 2f 25
7 I H H 2g 30
8 I H F 2c 55
9 I H Cl 2f 58
10 I H Cl 2f 48a
11 I OMe H 2h 42
12 I H Me 2i 35
a

Using 4CzIPn as photocatalyst.