Table 5. CF Synthesis of Carbonate 1a from EPI and CO₂^a.

entry	catalyst	T (°C)	EPIb (mol L–1)	Fc (mL min–1)	conv. (%)	sel. 1a (%)	productivity 1a (mmol g–1 h–1)
1	C4-500	200	0.3	0.01	>99	95	0.4
2	C4-500	175	0.3	0.01	>99	97	0.4
3	C4-500	150	0.3	0.01	>99	99	0.5
4	C4-500	200	0.3	0.1	48	87	1.9
5	C4-500	150	neat	0.01	75	95	10.5
6	C5-500	150	0.3	0.01	>99	99	0.5
7	C5-500	150	neat	0.01	>99	99	15.0

^aCO₂ flow rate was 1 mL min^–1 and the pressure was 100 bar in all cases.

^bEPI fed in an acetonitrile solution (0.3 M) or as such (neat).

^cF = flow rate of EPI (neat or in solution). Conversion of EPI and selectivity toward the carbonate 1a were determined by GC-FID analyses.