Table 1. Crystal Size and Textural Properties of the Calcined and Reduced Catalysts.
crystal
size (nm) |
||||||
---|---|---|---|---|---|---|
calcined |
reduced |
|||||
catalyst | NiOa | CeO2c | Nib | CeO2c | SBET(m2/g) | VT (cm3/g) |
Ni/CeO2 | 17.6 | 16.4 | 18.9 | 27.9 | 132 | 0.061 |
Na–Ni/CeO2 | 20.4 | 21.2 | 37.9 | 34.9 | 113 | 0.051 |
K–Ni/CeO2 | 17.5 | 18.5 | 28.3 | 34.9 | 106 | 0.046 |
Cs–Ni/CeO2 | 20.5 | 21.2 | 28.3 | 34.9 | 101 | 0.042 |
Calculated using the NiO(200) diffraction plane.
Calculated using the Ni0(111) diffraction plane.
Calculated using the CeO2(111) diffraction plane.