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. 2023 Jan 26;14(8):1960–1965. doi: 10.1039/d2sc06801j

Radical trapping experiments.

graphic file with name d2sc06801j-u4.jpg
Entry Conditions Yielda/%
2b 4b
1 2.5 mol% [RhCl(cod)]2 19 52
5.0 mol% depe, (365 nm)
2 (365 nm) 0 96b
3 2.5 mol% [RhCl(cod)]2 0 0
5.0 mol% depe
a

NMR yield.

b

The combined yield of 4b and p-methylbenzoic acid, which was generated by the reaction of 4b and HBpin under the reaction conditions.