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. 2022 May 10;61(20):7897–7909. doi: 10.1021/acs.inorgchem.2c00504

Table 1. Crystal Data and Measurement Details for [4]CF3SO3·0.5CH3CN.

  [4]CF3SO3·0.5CH3CN
formula C30H35.5F3Fe2N4.5O5PS
FW 770.86
T, K 100(2)
λ, Å 0.71073
crystal system monoclinic
space group P21/c
a, Å 10.4934(6)
b, Å 24.3729(14)
c, Å 12.9622(7)
β, deg 111.780(2)
cell volume, Å3 3078.5(3)
Z 4
Dc, g·cm–3 1.663
μ, mm–1 1.130
F(000) 1588
crystal size, mm 0.21 × 0.18 × 0.14
Θ limits, deg 1.671–26.999
reflections collected 45009
independent reflections 6652 [Rint = 0.0358]
data/restraints/parameters 6652/23/438
goodness of fit of F2 1.247
R1 (I > 2σ(I)) 0.0408
wR2 (all data) 0.0951
largest diff peak and hole, e Å–3 1.336/–0.500