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. 2023 Jan 26;123(4):1417–1551. doi: 10.1021/acs.chemrev.2c00534

Table 4. Nuclear Spin Eigenfunctions |X,m⟩ of the CH3 Moiety Grouped by Their Symmetry, where X Is the Symmetry of the State and m Is the Angular Momentum Quantum Number; c = ei/3a.

|A, 3/2⟩ = |ααα⟩
|A, 1/2⟩ = 1/3(|ααβ⟩ + |αβα⟩ + |βαα⟩)
|A, 1/2⟩ = 1/3(|ββα⟩ + |βαβ⟩ + |αββ⟩)
|A, −3/2⟩ = |βββ⟩
|Ea, 1/2⟩ = 1/3(|ααβ⟩ + c|αβα⟩ + c*|βαα⟩)
|Ea, −1/2 = 1/3(|ββα⟩ + c|βαβ⟩ + c*|αββ⟩)
|Eb, 1/2⟩ = 1/3(|ααβ⟩ + c*|αβα⟩ + c|βαα⟩)
|Eb, −1/2⟩ = 1/3(|ββα⟩ + c*|βαβ⟩ + c|αββ⟩)
a

Cyclic permutation of the spins leaves the A states unchanged, and the E states acquire a phase.