. 2023 Jan 30;11(2):405. doi: 10.3390/biomedicines11020405

Table 1.

Detected peak list from the UPLC-ESI-QTOF-MS/MS analysis of PF.

No.	Name	Formula	Mass (Da)	Expected	Adduct	Found at
No.	Name	Formula	Mass (Da)	RT (min)	Adduct	Mass (Da)
J1	Citric acid	C6H8O7	192.027	1.05	[M−H] ⁻	191.01958
J2	Guanosine	C11H15N5O4S	283.09167	1.31	[M+H] ⁺	284.09883
J2	Guanosine	C11H15N5O4S	283.09167	1.31	[M−H] ⁻	282.08411
J3	D-Pantothenic acid	C9H17NO5	219.11067	2.65	[M−H] ⁻	218.10336
J4	1-beta-D-glucopyranosyl-L-tryptophan	C17H22N2O7	366.1427	3.53	[M−H] ⁻	365.13525
J5	Tryptophan	C11H12N2O2	204.08988	3.71	[M+H] ⁺	205.09698
J5	Tryptophan	C11H12N2O2	204.08988	3.71	[M−H] ⁻	203.08254
J6	Quercetin 3-glucosyl-(1->3)-rhamnosyl-(1->6)-galactoside	C33H40O21	772.20621	5.32	[M+H] ⁺	773.2132
J6	Quercetin 3-glucosyl-(1->3)-rhamnosyl-(1->6)-galactoside	C33H40O21	772.20621	5.32	[M−H] ⁻	771.19788
J7	Umbelliferone	C9H6O3	162.03169	6.86	[M+H] ⁺	163.03866
J7	Umbelliferone	C9H6O3	162.03169	6.86	[M−H] ⁻	161.02466
J8	Rutin	C27H30O16	610.15339	7.20	[M+H] ⁺	611.16014
J8	Rutin	C27H30O16	610.15339	7.20	[M−H] ⁻	609.14549
J9	Isoquercitrin	C21H20O12	464.09548	7.48	[M−H] ⁻	463.08739
J10	Kaempferol 7-neohesperidoside	C27H30O15	594.15847	7.59	[M+H] ⁺	595.16579
J10	Kaempferol 7-neohesperidoside	C27H30O15	594.15847	7.59	[M-H] ⁻	593.15067
J11	Narirutin	C27H32O14	580.17921	7.99	[M+H] ⁺	581.18598
J11	Narirutin	C27H32O14	580.17921	7.99	[M−H] ⁻	579.17138
J12	Prunin (Naringenin-7-O-glucoside)	C21H22O10	434.1213	8.00	[M+H] ⁺	435.12884
J13	Naringenin	C15H12O5	272.06847	8.32	[M+H] ⁺	273.0757
J14	Naringin	C27H32O14	580.17921	8.32	[M+H] ⁺	581.18569
J14	Naringin	C27H32O14	580.17921	8.32	[M−H] ⁻	579.17147
J15	Hesperidin	C28H34O15	610.18977	8.60	[M+H] ⁺	611.19526
J15	Hesperidin	C28H34O15	610.18977	8.60	[M−H] ⁻	609.182
J16	Heralenol	C16H16O6	304.09469	9.84	[M+H] ⁺	305.10176
J17	Neoponcirin	C28H34O14	594.19486	10.55	[M+H] ⁺	595.20162
J17	Neoponcirin	C28H34O14	594.19486	10.55	[M−H] ⁻	595.20162
J18	Heralenol_1	C16H16O6	304.09469	10.58	[M+H] ⁺	305.10191
J19	Heptametoxiflavone	C22H24O9	432.14203	10.59	[M+H] ⁺	433.14889
J20	Isosakuranetin	C16H14O5	286.08412	10.89	[M+H] ⁺	287.09136
J21	Poncirin	C28H34O14	594.19486	10.90	[M+H] ⁺	595.20158
J21	Poncirin	C28H34O14	594.19486	10.90	[M−H] ⁻	593.18695
J22	Heptametoxiflavone_1	C22H24O9	432.14203	10.90	[M+H] ⁺	433.1487
J23	Isosakuranin	C22H24O10	448.13695	11.43	[M−H] ⁻	447.12857
J24	Bergapten	C12H8O4	216.04226	13.33	[M+H] ⁺	217.04951
J25	Isopimpinellin	C13H10O5	246.05282	13.5	[M+H] ⁺	247.06025
J26	Oxyimperatorin (Heraclenin)	C16H14O5	286.08412	14.23	[M+H] ⁺	287.09145
J27	Oxyimperatorin (Heraclenin)_1	C16H14O5	286.08412	15.44	[M+H] ⁺	287.09152
J28	Phellopterin	C17H16O5	300.09977	19.35	[M+H] ⁺	301.10746
J29	Auraptene	C19H22O3	298.15689	24.83	[M+H] ⁺	299.16419
J29	Auraptene	C19H22O3	298.15689	24.83	[M−H] ⁻	297.14938
P25	Limonene or α-Pinene	C10H16	136.1252	24.83	[M+H] ⁺	137.13244

PF, Ponciri Fructus Immaturus; UPLC-ESI-QTOF-MS/MS, ultra-performance liquid chromatography-electrospray ionization/quadrupole-time-of-flight high-definition mass spectrometry/mass spectrometry.