TABLE 1.
1H- and 13C-NMR data of terpentetriene and ent-clerod-3,13(16),14-triene
Group no.a, group | Terpentetriene
|
ent-clerod- 3,13(16), 14-triene
|
|
---|---|---|---|
C-13 | H-1b | C-13 | |
1, CH2 | 17.85 | ca. 1.42 (m), ca. 1.64 (m) | 18.3 |
2, CH2 | 26.85 | ca. 1.97 (m), ca. 2.04 (m) | 26.9 |
3, CH⩵ | 120.24 | 5.143 (br. s) | 120.4 |
4, C⩵ | 144.55 | 144.5 | |
5, C | 38.31 | 38.2 | |
6, CH2 | 30.20 | ca. 1.435 (13, 13, 6), ca. 1.46 (m) | 38.8 |
7, CH2 | 25.59 | 1.299 (14, 3, 3, 3), ca. 1.95 (13, 4, 4) | 27.5 |
8, CH | 35.16 | ca. 1.65 (m) | 38.3 |
9, C | 37.69 | 38.8 | |
10, CH | 45.13 | ca. 1.43 (m) | 46.5 |
11, CH2 | 38.31 | 1.179 (13, 13, 5), ca. 1.63 (m) | 37.5 |
12, CH2 | 24.57 | 2.136 (14, 14, 5), 2.185 (14, 14, 5) | 24.7 |
13, C⩵ | 147.75 | 147.6 | |
14, CH⩵ | 139.24 | 6.372 (18, 11) | 139.0 |
15, CH2⩵ | 113.02 | 5.242 (18, br), 5.043 (11, br) | 112.9 |
16, CH2⩵ | 115.24 | 4.99 (s) | 115.5 |
17, CH3 | 14.88 | 0.96 (7) | 16.1 |
18, CH3 | 20.63 | 1.051 (s) | 20.0 |
19, CH3 | 18.01 | 1.582 (br. s) | 16.0 |
20, CH3 | 20.38 | 0.968 (s) | 18.4 |