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. 2001 Oct;183(20):6085–6094. doi: 10.1128/JB.183.20.6085-6094.2001

TABLE 1.

1H- and 13C-NMR data of terpentetriene and ent-clerod-3,13(16),14-triene

Group no.a, group Terpentetriene
ent-clerod- 3,13(16), 14-triene
C-13 H-1b C-13
1, CH2 17.85 ca. 1.42 (m), ca. 1.64 (m) 18.3
2, CH2 26.85 ca. 1.97 (m), ca. 2.04 (m) 26.9
3, CH⩵ 120.24 5.143 (br. s) 120.4
4, C⩵ 144.55 144.5
5, C 38.31 38.2
6, CH2 30.20 ca. 1.435 (13, 13, 6), ca. 1.46 (m) 38.8
7, CH2 25.59 1.299 (14, 3, 3, 3), ca. 1.95 (13, 4, 4) 27.5
8, CH 35.16 ca. 1.65 (m) 38.3
9, C 37.69 38.8
10, CH 45.13 ca. 1.43 (m) 46.5
11, CH2 38.31 1.179 (13, 13, 5), ca. 1.63 (m) 37.5
12, CH2 24.57 2.136 (14, 14, 5), 2.185 (14, 14, 5) 24.7
13, C⩵ 147.75 147.6
14, CH⩵ 139.24 6.372 (18, 11) 139.0
15, CH2 113.02 5.242 (18, br), 5.043 (11, br) 112.9
16, CH2 115.24 4.99 (s) 115.5
17, CH3 14.88 0.96 (7) 16.1
18, CH3 20.63 1.051 (s) 20.0
19, CH3 18.01 1.582 (br. s) 16.0
20, CH3 20.38 0.968 (s) 18.4
a

The numbering corresponds to that in Fig. 3 and 4

b

Values in parentheses represent 1H-1H coupling constants in hertz.