Table 1. Studies Relating to the Doping of Porous BNa.
dopant | BN structure | dopant content | dopant chemical environment | dopant role in the study | nature of the study |
---|---|---|---|---|---|
C | porous BN, hBN nanosheets (BNNS) | 5–20 wt % C | basal planes | reduce bandgap, add sorption sites, add active catalytic sites | computational + experimental |
O | porous BN, BNNS, hBN monolayer | 5–20 at. % O | basal planes, edges | reduce bandgap, tune magnetic properties | computational + experimental |
C, O | porous BN | 8 at. % C,6 at. % O | basal planes | increase specific area and adsorption capacity | experimental |
Si | BN nanotubes | 0.08 at. % Si experimental, 5 at. % Si computational | basal planes | new synthesis technique, reduce bandgap | computational + experimental |
P | porous BN, hBN monolayer | 1–5 wt % P | basal planes | add sorption sites, reduce bandgap | computational + experimental |
S | hBN, hBN monolayer | basal planes | reduce bandgap, reduce electrical resistivity | computational + experimental | |
F | hBN monolayer | basal planes | reduce bandgap | computational | |
F, C, O | porous BN | basal planes | reduce bandgap, add sorption and catalytic sites | computational | |
Cl | hBN monolayer | basal planes | reduce bandgap | computational | |
metals (Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Mo, Ru, Rh, Pt, Pd, Au, Ag) | porous BN, hBN monolayer, BN nanobelts | composite form within and on monolayer surface basal planes | introduce plasmonic heating, reduce reaction-limiting potential, reduce bandgap, tune magnetic properties, create electric field within material | computational + experimental |
Full details in the Supporting Information, Table S1.