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. 2023 Feb 20;145(8):4462–4472. doi: 10.1021/jacs.2c10165

Table 3. Rate Constants Taken from Stern–Volmer Analysis of Kinetic Data in Acetonitrilea.

  BMQ+ MQ+ 3-acetylpyridine
[(bpy)2Ru(4,4′-dhbpy)]2+ 2.9 × 108 M–1 s–1 6.7 × 107 M–1 s–111
[(dpab)2Ru(4,4′-dhbpy)]2+ 1.6 × 107 M–1 s–1 1.1 × 107 M–1 s–1 1.3 × 107 M–1 s–1
a

For quenching rate constants with BMQ+ and MQ+ listed in the table, the total ion concentration of the solution was kept constant at 200 mM by addition of tetrabutyl ammonium hexafluorophosphate.