Table 4. Kinetic Isotope Effects for Excited State Quenching of Each Complex by MQ+ and BMQ+.
kH/kD MQ+ | kH/kD BMQ+ | |
---|---|---|
[(dpab)2Ru(4,4′-dhbpy)]2+ | 0.92 | 1.30 |
[(bpy)2Ru(4,4′-dhbpy)]2+ | 0.9011 | 1.04 |
kH/kD MQ+ | kH/kD BMQ+ | |
---|---|---|
[(dpab)2Ru(4,4′-dhbpy)]2+ | 0.92 | 1.30 |
[(bpy)2Ru(4,4′-dhbpy)]2+ | 0.9011 | 1.04 |