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. 2023 Feb 16;62(8):3503–3514. doi: 10.1021/acs.iecr.2c04132

Table 3. Elemental Analysis, Ash Content, and Estimated Higher Heating Value (HHV) of Dried Macroalga Residue (DMR), DMR < 500 μm Size Fraction (DMR<500), and Solid Residues after SW Treatment at Lab Scale and Pilot Scale, Expressed as % (w/w) ± Standard Deviationa.

sample C (%) N (%) H (%) S (%) O (%) ashes (%) H:C O:C N:C HHV (kJ/kg)
DMR 36 ± 1bc 4.2 ± 0.4c 5.9 ± 0.2e 0.21 ± 0.05c 32.3 ± 0.3e 21.8 ± 1.1d 2.0 ± 0.1d 0.68 ± 0.03c 0.11 ± 0.01c 14,987 ± 466b
DMR<500 38 ± 1c 3.6 ± 0.1b 5.6 ± 0.2cd 0.70 ± 0.05d 27.2 ± 1.4c 24.9 ± 1.0e 1.8 ± 0.2cd 0.54 ± 0.09b 0.08 ± 0.02b 15,789 ± 250d
lab 130 °C 34.8 ± 1.8b 3.8 ± 0.3bc 4.7 ± 0.3b 0.23 ± 0.04c 38 ± 2f 17.8 ± 1.3b 1.6 ± 0.1bc 0.83 ± 0.16d 0.09 ± 0.01b 15,217 ± 618c
lab 175 °C 36 ± 1bc 3.5 ± 0.1b 4.6 ± 0.2b 0.09 ± 0.08b 23.1 ± 1.4b 32.9 ± 0.7f 1.5 ± 0.1b 0.5 ± 0.1b 0.08 ± 0.02b 15,476 ± 318cd
pilot 130 °C 41.7 ± 0.9d 3.9 ± 0.1bc 5.5 ± 0.1c 0.20 ± 0.03c 28.5 ± 0.9c 20.2 ± 0.2c 1.6 ± 0.1bc 0.51 ± 0.07b 0.08 ± 0.01b 17,087 ± 200e
pilot 175 °C 40.7 ± 0.2d 4.2 ± 0.1c 5.80 ± 0.03de 0.22 ± 0.01c 30.4 ± 0.2d 18.7 ± 0.1b 1.7 ± 0.1bc 0.56 ± 0.01b 0.09 ± 0.01b 16,877 ± 38e
a

Values with different letters in each row are significantly different when applying the LSD method at p value ≤0.05 (C, carbon; H, hydrogen; N, nitrogen; S, sulfur; and O, oxygen (n = 3 technical replicates) (oxygen content was estimated by the difference).