Table 3. Elemental Analysis, Ash Content, and Estimated Higher Heating Value (HHV) of Dried Macroalga Residue (DMR), DMR < 500 μm Size Fraction (DMR<500), and Solid Residues after SW Treatment at Lab Scale and Pilot Scale, Expressed as % (w/w) ± Standard Deviationa.
sample | C (%) | N (%) | H (%) | S (%) | O (%) | ashes (%) | H:C | O:C | N:C | HHV (kJ/kg) |
---|---|---|---|---|---|---|---|---|---|---|
DMR | 36 ± 1bc | 4.2 ± 0.4c | 5.9 ± 0.2e | 0.21 ± 0.05c | 32.3 ± 0.3e | 21.8 ± 1.1d | 2.0 ± 0.1d | 0.68 ± 0.03c | 0.11 ± 0.01c | 14,987 ± 466b |
DMR<500 | 38 ± 1c | 3.6 ± 0.1b | 5.6 ± 0.2cd | 0.70 ± 0.05d | 27.2 ± 1.4c | 24.9 ± 1.0e | 1.8 ± 0.2cd | 0.54 ± 0.09b | 0.08 ± 0.02b | 15,789 ± 250d |
lab 130 °C | 34.8 ± 1.8b | 3.8 ± 0.3bc | 4.7 ± 0.3b | 0.23 ± 0.04c | 38 ± 2f | 17.8 ± 1.3b | 1.6 ± 0.1bc | 0.83 ± 0.16d | 0.09 ± 0.01b | 15,217 ± 618c |
lab 175 °C | 36 ± 1bc | 3.5 ± 0.1b | 4.6 ± 0.2b | 0.09 ± 0.08b | 23.1 ± 1.4b | 32.9 ± 0.7f | 1.5 ± 0.1b | 0.5 ± 0.1b | 0.08 ± 0.02b | 15,476 ± 318cd |
pilot 130 °C | 41.7 ± 0.9d | 3.9 ± 0.1bc | 5.5 ± 0.1c | 0.20 ± 0.03c | 28.5 ± 0.9c | 20.2 ± 0.2c | 1.6 ± 0.1bc | 0.51 ± 0.07b | 0.08 ± 0.01b | 17,087 ± 200e |
pilot 175 °C | 40.7 ± 0.2d | 4.2 ± 0.1c | 5.80 ± 0.03de | 0.22 ± 0.01c | 30.4 ± 0.2d | 18.7 ± 0.1b | 1.7 ± 0.1bc | 0.56 ± 0.01b | 0.09 ± 0.01b | 16,877 ± 38e |
Values with different letters in each row are significantly different when applying the LSD method at p value ≤0.05 (C, carbon; H, hydrogen; N, nitrogen; S, sulfur; and O, oxygen (n = 3 technical replicates) (oxygen content was estimated by the difference).