Table 7.
Doped Bi-based nanostructured photocatalysts for remediation of dye pollution.
Photocatalyst | Target dye pollutant | Optimum experimental conditions | Source of light | Degradation (%) | Ref. |
Remarks on active species | |||||
| |||||
Ag-BiOCl | rhodamine B | treatment time: 100 min; dosage of catalyst: 1 g/L; initial concentration of dye: 9.6 mg/L | visible light | 99 | [133] |
The photogenerated electrons converted adsorbed oxygen into •O2− radicals and with h+ contributed to the degradation process. | |||||
| |||||
Ce/Bi2O3, Nd/Bi2O3 | Acid Yellow 29, Coomassie brilliant blue (G250), Acid Green 25 | Reaction time: 120 min; dosage of catalyst: 1 g/L; the initial concentration of Acid Yellow 29: 0.1425 × 10−3 mg/L., of Coomassie brilliant blue (G250): 0.427 × 10−4 mg/L, and of Acid Green 25: 0.156 × 10−3 mg/L | visible light (halogen lamp) | 82.0–88.0, 74.0–84.0 | [134] |
•O2−, h+ and •OH were the active species during the degradation process. | |||||
| |||||
B/BiOBr | rhodamine B | optimum reaction time: 30 min; dosage of catalyst: 1 g/L; initial concentration of dye: 15 mg/L | visible light | 99.3 | [153] |
•OH played the main role in the degradation of rhodamine B. | |||||
| |||||
B/BiOCl | rhodamine B | optimum reaction time: 100 min; dosage of catalyst: 0.4 g/L; initial concentration of dye: 20 mg/L | visible light | 81.5 | [154] |
•O2− played the main role in the degradation of rhodamine B. | |||||
| |||||
C/BiOI | methyl orange | optimum reaction time: 60 min; dosage of catalyst: 0.1 g/L; initial concentration of dye: 10 mg/L. | visible light | 99.8 | [155] |
•O2− and holes played the main role in the degradation of methyl orange. | |||||
| |||||
In-BiOI | methyl orange | optimum reaction time: 120 min; dosage of catalyst: 0.1 g/L; initial concentration of dye: 10 mg/L. | visible light | 96.0 | [150] |
•O2− and holes played the main role in the degradation of methyl orange. |