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. 2023 Feb 27;123(5):2436–2608. doi: 10.1021/acs.chemrev.2c00799

Figure 37.

Figure 37

(a) Steel making through the classical blast furnace and downstream basic oxygen converter route with the use of CO as reductant in the blast furnace, producing ∼1.9–2.2 tonnes CO2 per ton of steel produced. This qualifies the blast furnace process as the largest single CO2 emitter on the globe. (b) Direct reduction: solid-state reduction of hematite (or magnetite) with either methane or hydrogen (or reductant mixtures). The hydrogen-based direct reduction variant is capable of reducing the carbon footprint of iron making by 70−80% when using hydrogen from renewable production. (c) Reductant-containing plasma (e.g., hydrogen-based plasma) atmospheres in electric arc furnaces used for liquid-state oxide reduction (also called hydrogen plasma smelting). This furnace could also be additionally charged with steel scrap. This means that plasma reduction offers an all-in-one process of melting, mixing, and liquid-state reduction.