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. 2023 Feb 27;123(5):2436–2608. doi: 10.1021/acs.chemrev.2c00799

Table 43. Approaches toward More Sustainable Electrolysis-Based Aluminium Production.

Longer-lasting, inert and carbon-free cathodes
Replacement of anodes consisting of petroleum coke and tar pitch, consumed in the electrolysis in an anode reaction
Use of renewable electrical energy sources for electrolysis
Higher cell efficiency and avoidance of cell freezing also for seasonally variable power availability from renewable electrical energy sources
Electrolysis cell operation under variable electrical power supply
Low-temperature electrolytes
Reduction of the cryolite melting point
Use of red mud as a feedstock resource instead of dumping
Less electrode reactions
Replace techniques of leaching in an autoclave, calcination in a rotary kiln, and electrolysis in cells with Söderberg anodes with the altogether up to 20% lower-energy solutions of leaching in a tubular reactor, calcination in a fluidized bed reactor, and electrolysis in cells with prebaked anodes