Supramolecular Chemistry And Self-assembly Special Feature: A peptide template as an allosteric supramolecular catalyst for the cleavage of phosphate esters -- Data Supplement - Supporting Information -- Proceedings of the National Academy of Sciences

Supporting information for Scarso et al. (April 9, 2002) Proc. Natl. Acad. Sci. USA, 10.1073/pnas.072642699.

Fig. 9.
Rotating-frame Overhauser effect spectroscopy spectrum at 312 K of P1 in H₂O/D₂O 9:1; the labels in blue are related to dipolar correlations that suggests a 3₁₀-helical conformation. The green arrow shows the lack of the cross-peak of Ac,N(i, i + 4) between the CH₃-CO– and the NH of (S)-2-amino-3-[1-(Tacn)]propanoic acid. The red arrow shows the lack of the cross-peak of a,N(i, i + 4) between CH-a (S)-2-amino-3-[1-(Tacn)]propanoic acid 4 and –NH-CH₃.