Entropically driven self-assembly of multichannel rosette nanotubes -- Data Supplement - Supporting Information -- Proceedings of the National Academy of Sciences

Supporting information for Fenniri et al. (March 12, 2002) Proc. Natl. Acad. Sci. USA, 10.1073/pnas.032527099.

Fig. 7.
1D ¹H–NMR spectrum (600 MHz) of a 0.025 M solution of 2 in 90% H₂O/D₂O at 2°C. This spectrum shows that there are two sets of resonances for the imino and methyl protons with a population ratio of 3:1. This ratio is insensitive to temperature (2–42°C) and concentration (0.001–0.025 M) (data not shown). The proton assignments are as follows: d (ppm), 9.17 (^CH, s, 1H ´ 75%), 9.14 (^CH, s, 1H ´ 25%), 8.61 (^AH, q, ³J = 4.8 Hz, 1H ´ 25%), 8.45 (^BH, s, 2H ´ 75%), 8.42 (^BH, s, 2H ´ 25%), 7.72 (^AH, q, ³J = 4.8 Hz, 1H ´ 75%), 6.93 (C₃₁H, d, ³J = 8.4 Hz, 1H), 6.85 (C₂₈H, s, ⁴J = 2.4 Hz, 1H), 6.82 (C₃₂H, dd, ³J = 8.4 Hz, ⁴J = 2.4 Hz, 1H), 4.12 (C₆H, br, t, 2H), 3.90–3.83 (C₇H, C₃₃H, C₄₀H, m, 6H), 3.73–3.64 (C₃₄H–C₃₉H, m, 16H), 2.98 (C₉H, d, ³J = 4.8 Hz, 3H ´ 25%), 2.94 (C₉H, d, ³J = 4.8 Hz, 3H ´ 75%). C₇NH was suppressed with the solvent peak.