data_squeezed _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C20 H30 F12 N4 P2 Ru' _chemical_formula_weight 717.49 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'F' 'F' 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'P' 'P' 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Ru' 'Ru' -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting Monoclinic _symmetry_space_group_name_H-M P2(1)/n loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' _cell_length_a 8.6230(2) _cell_length_b 34.7990(10) _cell_length_c 9.8620(3) _cell_angle_alpha 90.00 _cell_angle_beta 114.4360(10) _cell_angle_gamma 90.00 _cell_volume 2694.22(13) _cell_formula_units_Z 4 _cell_measurement_temperature 293(2) _cell_measurement_reflns_used 3846 _cell_measurement_theta_min 2.34 _cell_measurement_theta_max 24.75 _exptl_crystal_description lath _exptl_crystal_colour orange _exptl_crystal_size_max 0.57 _exptl_crystal_size_mid 0.19 _exptl_crystal_size_min 0.10 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.769 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1440 _exptl_absorpt_coefficient_mu 0.802 _exptl_absorpt_correction_type SADABS _exptl_absorpt_correction_T_min 0.831 _exptl_absorpt_correction_T_max 1.000 _exptl_absorpt_process_details ? _exptl_special_details ; ? ; _diffrn_ambient_temperature 293(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Bruker P4' _diffrn_measurement_method '\w scans' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 18803 _diffrn_reflns_av_R_equivalents 0.0505 _diffrn_reflns_av_sigmaI/netI 0.0659 _diffrn_reflns_limit_h_min -11 _diffrn_reflns_limit_h_max 11 _diffrn_reflns_limit_k_min -47 _diffrn_reflns_limit_k_max 41 _diffrn_reflns_limit_l_min -13 _diffrn_reflns_limit_l_max 11 _diffrn_reflns_theta_min 2.34 _diffrn_reflns_theta_max 29.06 _reflns_number_total 6572 _reflns_number_gt 4950 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'Bruker XSCANS' _computing_cell_refinement 'Bruker XSCANS' _computing_data_reduction 'Bruker SHELXTL' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Bruker SHELXTL' _computing_publication_material 'Bruker SHELXTL' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0519P)^2^+8.2775P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 6572 _refine_ls_number_parameters 328 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0808 _refine_ls_R_factor_gt 0.0575 _refine_ls_wR_factor_ref 0.1368 _refine_ls_wR_factor_gt 0.1276 _refine_ls_goodness_of_fit_ref 1.040 _refine_ls_restrained_S_all 1.040 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group F1 F 1.4910(6) 0.23879(13) 0.6819(5) 0.0870(16) Uani 1 1 d . . . F2 F 1.4611(7) 0.15711(13) 0.5373(6) 0.108(2) Uani 1 1 d . . . F3 F 1.5961(6) 0.21017(16) 0.5428(6) 0.0926(16) Uani 1 1 d . . . F4 F 1.6294(5) 0.18291(13) 0.7572(4) 0.0710(12) Uani 1 1 d . . . F5 F 1.3491(7) 0.1844(2) 0.6820(8) 0.156(3) Uani 1 1 d . . . F6 F 1.3090(5) 0.21177(11) 0.4717(4) 0.0666(12) Uani 1 1 d . . . F7 F 1.3881(4) 0.06428(10) 0.5180(3) 0.0401(8) Uani 1 1 d . . . F8 F 1.4131(4) 0.04124(10) 0.8405(3) 0.0385(8) Uani 1 1 d . . . F9 F 1.5344(4) 0.08658(9) 0.7529(3) 0.0384(7) Uani 1 1 d . . . F10 F 1.5562(4) 0.02415(10) 0.7024(3) 0.0449(8) Uani 1 1 d . . . F11 F 1.2680(4) 0.01871(9) 0.6081(3) 0.0407(8) Uani 1 1 d . . . F12 F 1.2473(4) 0.08111(10) 0.6547(4) 0.0426(8) Uani 1 1 d . . . C1 C 0.8070(3) 0.14465(8) 0.4483(2) 0.0218(9) Uani 1 1 d G . . C2 C 0.7177(4) 0.11045(7) 0.4002(3) 0.0223(9) Uani 1 1 d G . . C3 C 0.5909(3) 0.10759(6) 0.2565(3) 0.0203(9) Uani 1 1 d G . . C4 C 0.5534(3) 0.13893(8) 0.1608(2) 0.0232(10) Uani 1 1 d G . . C5 C 0.6427(4) 0.17313(6) 0.2088(3) 0.0221(9) Uani 1 1 d G . . C6 C 0.7695(3) 0.17599(6) 0.3525(3) 0.0225(9) Uani 1 1 d G . . C7 C 0.9460(6) 0.14772(15) 0.6086(5) 0.0316(11) Uani 1 1 d . . . H7A H 0.9953 0.1730 0.6244 0.047 Uiso 1 1 calc R . . H7B H 1.0330 0.1289 0.6231 0.047 Uiso 1 1 calc R . . H7C H 0.8964 0.1432 0.6781 0.047 Uiso 1 1 calc R . . C8 C 0.7645(7) 0.07561(14) 0.5072(6) 0.0321(11) Uani 1 1 d . . . H8A H 0.8541 0.0827 0.6009 0.048 Uiso 1 1 calc R . . H8B H 0.8021 0.0548 0.4645 0.048 Uiso 1 1 calc R . . H8C H 0.6662 0.0677 0.5225 0.048 Uiso 1 1 calc R . . C9 C 0.4925(6) 0.06945(13) 0.2080(5) 0.0269(10) Uani 1 1 d . . . H9A H 0.4094 0.0716 0.1070 0.040 Uiso 1 1 calc R . . H9B H 0.4363 0.0639 0.2718 0.040 Uiso 1 1 calc R . . H9C H 0.5707 0.0491 0.2150 0.040 Uiso 1 1 calc R . . C10 C 0.4120(6) 0.13641(15) -0.0014(5) 0.0317(11) Uani 1 1 d . . . H10A H 0.3622 0.1112 -0.0184 0.047 Uiso 1 1 calc R . . H10B H 0.4614 0.1412 -0.0709 0.047 Uiso 1 1 calc R . . H10C H 0.3256 0.1552 -0.0145 0.047 Uiso 1 1 calc R . . C11 C 0.6054(7) 0.20797(15) 0.1039(6) 0.0363(12) Uani 1 1 d . . . H11A H 0.6783 0.2289 0.1556 0.054 Uiso 1 1 calc R . . H11B H 0.4886 0.2155 0.0723 0.054 Uiso 1 1 calc R . . H11C H 0.6262 0.2012 0.0185 0.054 Uiso 1 1 calc R . . C12 C 0.8668(7) 0.21387(14) 0.4086(6) 0.0337(12) Uani 1 1 d . . . H12A H 0.9492 0.2107 0.5094 0.051 Uiso 1 1 calc R . . H12B H 0.7881 0.2338 0.4046 0.051 Uiso 1 1 calc R . . H12C H 0.9239 0.2208 0.3467 0.051 Uiso 1 1 calc R . . C13 C 1.0131(7) 0.16319(16) 0.0797(6) 0.0378(13) Uani 1 1 d . . . H13A H 0.9989 0.1893 0.1069 0.045 Uiso 1 1 calc R . . H13B H 1.0427 0.1641 -0.0051 0.045 Uiso 1 1 calc R . . C14 C 1.1503(7) 0.14330(17) 0.2079(6) 0.0375(13) Uani 1 1 d . . . H14A H 1.1718 0.1181 0.1776 0.045 Uiso 1 1 calc R . . H14B H 1.2549 0.1581 0.2418 0.045 Uiso 1 1 calc R . . N1 N 0.8813(3) 0.06975(6) 0.2029(3) 0.0193(8) Uani 1 1 d G . . C15 C 1.0175(3) 0.04922(7) 0.3056(2) 0.0282(11) Uani 1 1 d G . . H15 H 1.0922 0.0610 0.3928 0.034 Uiso 1 1 calc R . . C16 C 1.0421(3) 0.01103(7) 0.2780(3) 0.0294(11) Uani 1 1 d G . . H16 H 1.1333 -0.0027 0.3468 0.035 Uiso 1 1 calc R . . C17 C 0.9305(4) -0.00662(6) 0.1477(3) 0.0206(9) Uani 1 1 d G . . C18 C 0.7943(3) 0.01391(7) 0.0450(3) 0.0241(10) Uani 1 1 d G . . H18 H 0.7196 0.0021 -0.0422 0.029 Uiso 1 1 calc R . . C19 C 0.7697(3) 0.05209(7) 0.0726(3) 0.0222(9) Uani 1 1 d G . . H19 H 0.6785 0.0658 0.0038 0.027 Uiso 1 1 calc R . . C20 C 0.9554(6) -0.04611(14) 0.1163(5) 0.0237(10) Uani 1 1 d . . . Ru1 Ru 0.82600(4) 0.126930(10) 0.24244(4) 0.01690(11) Uani 1 1 d . . . P2 P 1.40159(16) 0.05285(4) 0.67924(13) 0.0251(3) Uani 1 1 d . . . P1 P 1.47325(18) 0.19769(4) 0.61311(16) 0.0357(3) Uani 1 1 d . . . N4 N 1.0928(5) 0.13964(12) 0.3291(5) 0.0281(9) Uani 1 1 d . . . H4A H 1.1138 0.1617 0.3811 0.034 Uiso 1 1 calc R . . H4B H 1.1519 0.1208 0.3915 0.034 Uiso 1 1 calc R . . N2 N 0.9761(5) -0.07665(12) 0.0872(4) 0.0281(9) Uani 1 1 d . . . N3 N 0.8534(5) 0.14102(12) 0.0417(4) 0.0271(9) Uani 1 1 d . . . H3A H 0.8568 0.1193 -0.0068 0.033 Uiso 1 1 calc R . . H3B H 0.7637 0.1551 -0.0184 0.033 Uiso 1 1 calc R . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 F1 0.074(3) 0.071(3) 0.092(3) -0.041(3) 0.010(3) 0.018(2) F2 0.117(4) 0.049(3) 0.094(4) -0.021(3) -0.023(3) 0.016(3) F3 0.086(3) 0.124(4) 0.102(4) 0.022(3) 0.074(3) 0.020(3) F4 0.062(3) 0.079(3) 0.048(2) 0.012(2) -0.002(2) 0.005(2) F5 0.070(4) 0.258(9) 0.153(6) 0.122(6) 0.059(4) -0.004(4) F6 0.056(2) 0.051(2) 0.060(2) 0.0041(19) -0.0084(19) 0.0092(19) F7 0.0345(17) 0.061(2) 0.0223(15) 0.0073(14) 0.0096(13) -0.0007(15) F8 0.0341(17) 0.059(2) 0.0178(14) -0.0007(13) 0.0063(13) -0.0150(15) F9 0.0327(16) 0.0402(18) 0.0310(16) 0.0006(13) 0.0019(13) -0.0119(13) F10 0.0374(18) 0.053(2) 0.0370(18) 0.0055(15) 0.0082(15) 0.0173(15) F11 0.0418(18) 0.0380(18) 0.0278(16) -0.0032(13) -0.0002(14) -0.0136(14) F12 0.0304(17) 0.050(2) 0.0401(18) -0.0073(15) 0.0070(14) 0.0093(14) C1 0.023(2) 0.027(2) 0.021(2) -0.0039(18) 0.0144(19) 0.0002(18) C2 0.021(2) 0.023(2) 0.026(2) 0.0026(18) 0.0133(19) 0.0009(18) C3 0.024(2) 0.020(2) 0.021(2) -0.0003(17) 0.0132(19) -0.0001(17) C4 0.021(2) 0.023(2) 0.027(2) -0.0028(18) 0.010(2) 0.0017(17) C5 0.024(2) 0.016(2) 0.027(2) 0.0013(18) 0.012(2) 0.0066(17) C6 0.023(2) 0.021(2) 0.029(2) -0.0096(19) 0.017(2) -0.0038(18) C7 0.032(3) 0.036(3) 0.024(3) -0.002(2) 0.008(2) 0.000(2) C8 0.032(3) 0.030(3) 0.032(3) 0.009(2) 0.010(2) 0.001(2) C9 0.024(2) 0.026(2) 0.031(3) -0.001(2) 0.011(2) -0.0061(19) C10 0.024(2) 0.038(3) 0.027(3) 0.002(2) 0.005(2) 0.000(2) C11 0.040(3) 0.025(3) 0.038(3) 0.009(2) 0.011(2) 0.003(2) C12 0.044(3) 0.025(3) 0.035(3) -0.010(2) 0.019(3) -0.009(2) C13 0.053(4) 0.031(3) 0.049(3) -0.002(2) 0.040(3) -0.009(2) C14 0.032(3) 0.047(3) 0.044(3) -0.018(3) 0.026(3) -0.009(2) N1 0.0199(19) 0.0180(19) 0.0183(18) -0.0016(14) 0.0060(16) 0.0027(14) C15 0.027(2) 0.025(3) 0.024(2) -0.0040(19) 0.002(2) 0.0067(19) C16 0.029(3) 0.026(3) 0.023(2) -0.002(2) 0.000(2) 0.006(2) C17 0.022(2) 0.022(2) 0.020(2) 0.0011(17) 0.0106(18) 0.0043(17) C18 0.023(2) 0.026(2) 0.018(2) -0.0031(18) 0.0034(19) 0.0008(18) C19 0.021(2) 0.024(2) 0.018(2) -0.0022(18) 0.0042(18) 0.0026(17) C20 0.023(2) 0.026(3) 0.020(2) 0.0010(18) 0.0068(19) 0.0020(18) Ru1 0.01778(17) 0.01606(17) 0.01712(17) -0.00193(14) 0.00746(13) 0.00012(14) P2 0.0236(6) 0.0286(7) 0.0184(6) 0.0001(5) 0.0039(5) -0.0016(5) P1 0.0320(7) 0.0377(8) 0.0321(7) 0.0014(6) 0.0079(6) 0.0025(6) N4 0.024(2) 0.030(2) 0.032(2) -0.0113(18) 0.0128(18) -0.0064(17) N2 0.035(2) 0.023(2) 0.026(2) -0.0022(17) 0.0124(19) 0.0035(17) N3 0.033(2) 0.025(2) 0.027(2) 0.0029(17) 0.0164(19) 0.0062(17) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag F1 P1 1.563(4) . ? F2 P1 1.581(5) . ? F3 P1 1.549(4) . ? F4 P1 1.585(4) . ? F5 P1 1.557(5) . ? F6 P1 1.599(4) . ? F7 P2 1.596(3) . ? F8 P2 1.604(3) . ? F9 P2 1.590(3) . ? F10 P2 1.605(3) . ? F11 P2 1.601(3) . ? F12 P2 1.590(3) . ? C1 C2 1.3900 . ? C1 C6 1.3900 . ? C1 C7 1.543(5) . ? C1 Ru1 2.191(3) . ? C2 C3 1.3900 . ? C2 C8 1.547(5) . ? C2 Ru1 2.197(3) . ? C3 C4 1.3900 . ? C3 C9 1.541(5) . ? C3 Ru1 2.195(3) . ? C4 C5 1.3900 . ? C4 C10 1.562(5) . ? C4 Ru1 2.187(3) . ? C5 C6 1.3900 . ? C5 C11 1.539(5) . ? C5 Ru1 2.182(3) . ? C6 C12 1.537(5) . ? C6 Ru1 2.184(3) . ? C13 N3 1.485(6) . ? C13 C14 1.496(8) . ? C14 N4 1.476(6) . ? N1 C15 1.3900 . ? N1 C19 1.3900 . ? N1 Ru1 2.1198(19) . ? C15 C16 1.3900 . ? C16 C17 1.3900 . ? C17 C18 1.3900 . ? C17 C20 1.444(5) . ? C18 C19 1.3900 . ? C20 N2 1.134(6) . ? Ru1 N4 2.143(4) . ? Ru1 N3 2.145(4) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C2 C1 C6 120.0 . . ? C2 C1 C7 119.6(3) . . ? C6 C1 C7 120.4(3) . . ? C2 C1 Ru1 71.74(9) . . ? C6 C1 Ru1 71.18(9) . . ? C7 C1 Ru1 130.1(3) . . ? C1 C2 C3 120.0 . . ? C1 C2 C8 119.2(3) . . ? C3 C2 C8 120.8(3) . . ? C1 C2 Ru1 71.32(9) . . ? C3 C2 Ru1 71.46(9) . . ? C8 C2 Ru1 128.3(3) . . ? C4 C3 C2 120.0 . . ? C4 C3 C9 121.4(3) . . ? C2 C3 C9 118.6(3) . . ? C4 C3 Ru1 71.21(9) . . ? C2 C3 Ru1 71.63(9) . . ? C9 C3 Ru1 130.4(2) . . ? C5 C4 C3 120.0 . . ? C5 C4 C10 119.0(3) . . ? C3 C4 C10 121.0(3) . . ? C5 C4 Ru1 71.24(9) . . ? C3 C4 Ru1 71.80(9) . . ? C10 C4 Ru1 129.1(3) . . ? C4 C5 C6 120.0 . . ? C4 C5 C11 120.9(3) . . ? C6 C5 C11 119.1(3) . . ? C4 C5 Ru1 71.66(9) . . ? C6 C5 Ru1 71.52(9) . . ? C11 C5 Ru1 128.3(3) . . ? C5 C6 C1 120.0 . . ? C5 C6 C12 120.7(3) . . ? C1 C6 C12 119.3(3) . . ? C5 C6 Ru1 71.35(9) . . ? C1 C6 Ru1 71.77(9) . . ? C12 C6 Ru1 130.4(3) . . ? N3 C13 C14 107.4(4) . . ? N4 C14 C13 108.2(4) . . ? C15 N1 C19 120.0 . . ? C15 N1 Ru1 122.34(13) . . ? C19 N1 Ru1 117.55(13) . . ? C16 C15 N1 120.0 . . ? C15 C16 C17 120.0 . . ? C16 C17 C18 120.0 . . ? C16 C17 C20 120.7(2) . . ? C18 C17 C20 119.3(2) . . ? C19 C18 C17 120.0 . . ? C18 C19 N1 120.0 . . ? N2 C20 C17 177.4(5) . . ? N1 Ru1 N4 88.91(13) . . ? N1 Ru1 N3 85.73(13) . . ? N4 Ru1 N3 79.10(16) . . ? N1 Ru1 C5 150.21(10) . . ? N4 Ru1 C5 119.96(13) . . ? N3 Ru1 C5 92.35(12) . . ? N1 Ru1 C6 159.87(10) . . ? N4 Ru1 C6 93.67(12) . . ? N3 Ru1 C6 114.37(13) . . ? C5 Ru1 C6 37.1 . . ? N1 Ru1 C4 113.63(10) . . ? N4 Ru1 C4 157.02(13) . . ? N3 Ru1 C4 97.40(13) . . ? C5 Ru1 C4 37.1 . . ? C6 Ru1 C4 66.84(6) . . ? N1 Ru1 C1 122.92(10) . . ? N4 Ru1 C1 92.97(12) . . ? N3 Ru1 C1 150.39(13) . . ? C5 Ru1 C1 66.81(6) . . ? C6 Ru1 C1 37.0 . . ? C4 Ru1 C1 78.83(6) . . ? N1 Ru1 C3 90.45(10) . . ? N4 Ru1 C3 154.90(13) . . ? N3 Ru1 C3 125.87(13) . . ? C5 Ru1 C3 66.75(6) . . ? C6 Ru1 C3 78.83(6) . . ? C4 Ru1 C3 37.0 . . ? C1 Ru1 C3 66.58(6) . . ? N1 Ru1 C2 94.55(10) . . ? N4 Ru1 C2 118.19(13) . . ? N3 Ru1 C2 162.71(13) . . ? C5 Ru1 C2 78.83(6) . . ? C6 Ru1 C2 66.68(6) . . ? C4 Ru1 C2 66.62(6) . . ? C1 Ru1 C2 36.9 . . ? C3 Ru1 C2 36.9 . . ? F9 P2 F12 90.70(18) . . ? F9 P2 F7 90.73(17) . . ? F12 P2 F7 88.99(18) . . ? F9 P2 F8 89.76(16) . . ? F12 P2 F8 90.65(18) . . ? F7 P2 F8 179.40(19) . . ? F9 P2 F11 178.92(18) . . ? F12 P2 F11 89.26(18) . . ? F7 P2 F11 90.34(17) . . ? F8 P2 F11 89.16(16) . . ? F9 P2 F10 89.74(18) . . ? F12 P2 F10 179.4(2) . . ? F7 P2 F10 90.62(18) . . ? F8 P2 F10 89.73(18) . . ? F11 P2 F10 90.31(19) . . ? F3 P1 F1 88.6(3) . . ? F3 P1 F5 178.8(4) . . ? F1 P1 F5 92.6(4) . . ? F3 P1 F2 87.8(3) . . ? F1 P1 F2 176.3(4) . . ? F5 P1 F2 91.0(4) . . ? F3 P1 F4 90.4(3) . . ? F1 P1 F4 90.8(2) . . ? F5 P1 F4 89.7(3) . . ? F2 P1 F4 90.0(2) . . ? F3 P1 F6 92.7(3) . . ? F1 P1 F6 89.4(2) . . ? F5 P1 F6 87.2(3) . . ? F2 P1 F6 90.0(2) . . ? F4 P1 F6 176.9(3) . . ? C14 N4 Ru1 111.1(3) . . ? C13 N3 Ru1 109.3(3) . . ? _diffrn_measured_fraction_theta_max 0.911 _diffrn_reflns_theta_full 29.06 _diffrn_measured_fraction_theta_full 0.911 _refine_diff_density_max 1.047 _refine_diff_density_min -0.930 _refine_diff_density_rms 0.128