Holzwarth et al. 10.1073/pnas.0505371103. |
Supporting Text
Supporting Figure 4
Supporting Figure 5
Supporting Table 1
Supporting Figure 6
Supporting Figure 7
Supporting Figure 8
Supporting Figure 9
Supporting Figure 10
Supporting Figure 4
Fig. 4. Results from the application of the kinetic model (A) proposed by Groot et al. (1, 2) to our transient absorption data of isolated D1-D2 RCs (Fig. 5). The resulting SADS are shown in B.
1. van Mourik, F., Groot, M.-L., van Grondelle, R., Dekker, J. P. & van Stokkum, I. H. M. (2004) Phys. Chem. Chem. Phys. 6, 48204824.
2. Groot, M.-L., Pawlowicz, N. P., van der Wilderen, L. J. G. W., Breton, J., van Stokkum, I. H. M. & van Grondelle, R. (2005) Proc. Natl. Acad. Sci. USA 102, 1308713092.
Fig. 5. Original transient absorption 3D surfaces (before binning; see Supporting Text) for isolated D1-D2 RC excited at 681 nm. (A) The 620- to 740-nm detection range. (B) The 510- to 630-nm detection range (Qx region). Note that the absorbance scale is reversed (negative is up) for better visibility in the presentation.
Fig. 6. Original transient absorption kinetics (thin lines) for isolated D1-D2 RCs (cf. Fig. 5) at the indicated detection wavelengths and theoretical curves (thick lines).
Fig. 7. Original transient absorption 3D surfaces (before binning; see Supporting Text) for intact PSII cores with open RCs excited at 663 nm. (A) The 620- to 740-nm detection range. (B) The 510- to 630-nm detection range (Qx region). Note that the absorbance scale is reversed (negative is up) for better visibility in the presentation.
Fig. 8. Original transient absorption kinetics (thin lines) for intact PSII cores (cf. Fig. 7) at the indicated detection wavelengths, and theoretical curves (thick lines).
Fig. 10. Results of the kinetic compartment analysis for intact PSII cores. (A) Time-dependent populations of the intermediates of intact PSII cores as resulting from the kinetic model in Fig. 3C. The first radical pair RP1 reaches its maximum of 30% relative population at »6 ps after excitation. (B) Amplitude matrix (weighted eigenvectors) for the kinetic model in Fig. 3C. See the Fig. 9 legend for a detailed explanation.
Table 1. Qualitative analysis of lifetime distributions in the LFD maps of the isolated D1-D2 RC
Shown are the observed maxima and approximate wavelength ranges (nm) of the lifetime distributions (cf. Fig. 1) in the various detection wavelength ranges. w. weak band.