Bioinorganic Chemistry Special Feature: How does cyanide inhibit superoxide reductase? Insight from synthetic FeIIIN4S model complexes -- Data Supplement - Supporting Information -- Proceedings of the National Academy of Sciences

Supporting information for Shearer et al. (2003) Proc. Natl. Acad. Sci. USA, 10.1073/pnas.0637029100

Fig. 13.
Cyclic voltammogram (200 mV/sec) of [Fe^III(S^Me2N₄(tren))(OAc)](BPh₄) (6) showing its quasireversible reduction in acetonitrile (100 mM Bu₄ⁿNPF₆). Peak potentials vs. SCE are indicated. The peak that develops at –50 mV during the reverse scan corresponds to five-coordinate [Fe^II(S^Me2N₄(tren))]⁺ (1), which forms on dissociation of acetate from the reduced derivative of 6.