Inhomogeneous dynamics in confined water nanodroplets -- Dokter et al. 103 (42): 15355 Data Supplement - HTML Page - index.htslp -- Proceedings of the National Academy of Sciences

Doktor et al. 10.1073/pnas.0603239103.

Supporting Information

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Supporting Text
Supporting Table 1
Supporting Figure 5
Supporting Figure 6

Supporting Figure 5

Fig. 5. Spectral amplitudes of the core (fast) and interfacial (slow) components in the vibrational relaxation for all studied sizes of reverse micelles, obtained from a global fit to the vibrational relaxation curves, obtained by measuring the rotation free pump-probe signal Da_RF. (Lower Right) The relative core and interfacial fractions, which are obtained by spectrally integrating the positive (bleaching) part of the spectrum for each of the two components (see Table 1).

Supporting Figure 6

Fig. 6. Orientational relaxation of the OH-stretch vibration of water in various degrees of confinement. For six samples of different sizes of micelles, we compare the anisotropy decay at a blue and red absorption frequency around 3,550 and 3,390 cm^-1, respectively.