Coordination Chemistry of Saturated Molecules Special Feature: C-C {sigma} complexes of rhodium -- Brayshaw et al. 104 (17): 6921 Data Supplement - HTML Page - index.htslp -- Proceedings of the National Academy of Sciences

Brayshaw et al. 10.1073/pnas.0609824104.

Supporting Information

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SI Table 2
SI Figure 4
SI Table 3
SI Figure 5
SI Table 4
SI Table 5
SI Table 6
SI Table 7
SI Dataset
SI Text

SI Figure 4

Fig. 4. Comparison of the Binor-S-derived fragment in 1-3 and other crystallographically determined Binor-S structures [Boer FP, Neuman MA, Roth RJ, Katz TJ (1971) J Am Chem Soc 93: 4436-4442; D'Accolti L, Fusco C, Lucchini V, Carpenter GB, Curci R (2001) J Org Chem 66:9063-9066]. Average data from complexes 1-3 are reported.

SI Figure 5

Fig. 5. Variable temperature ¹H NMR spectra in the alkyl region of complex 1 with the H(11)/(15)/H(21)/(25) and H(26)/H(16) pairs highlighted. Other signals are due to Binor-S and ⁱPr. There are no signals to high-field d 0 that would be indicative of an agostic interaction.